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Practical Exercises in Physical Chemistry
Practical Exercises in Physical Chemistry

... Although, the precise mechanism of the dissociation is complex, in the first approximation the decay can be described using the first-order rate law for the concentrations. The dissociation of Mn(III) tris-oxalate is relatively slow since in order to transform the complex into the products, a certai ...
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... If 4.168 kJ of heat is added to a calorimeter containing 75.40 g of water, the temperature of the water and the calorimeter increases from 24.58C to 35.82C. Calculate the heat capacity of the calorimeter (in J/C). The specific heat of water is 4.184 J/gC. a. 622 J/C b. 55.34 J/C c. 315.5 J/C ...
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... Strategy: The relationship between the concentration of a reactant at different times in a first-order reaction is given by Equations (14.3) and (14.4) of the text. We are asked to determine the time required for 95% of the phosphine to decompose. If we initially have 100% of the compound and 95% ha ...
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... Strategy: The relationship between the concentration of a reactant at different times in a first-order reaction is given by Equations (14.3) and (14.4) of the text. We are asked to determine the time required for 95% of the phosphine to decompose. If we initially have 100% of the compound and 95% ha ...
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... body, and the atmosphere of a large city. In this chapter, the discussion of reactors is limited to topics germane to the determination of reaction rates. Later in this text, strategies for attacking the problems of mathematically describing and predicting behavior of reactors in general are present ...
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Title Decomposition studies of isopropanol in a

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Reaction progress kinetic analysis

In chemistry, reaction progress kinetic analysis (RPKA) is a subset of a broad range of kinetic techniques utilized to determine the rate laws of chemical reactions and to aid in elucidation of reaction mechanisms. While the concepts guiding reaction progress kinetic analysis are not new, the process was formalized by Professor Donna Blackmond (currently at Scripps Research Institute) in the late 1990s and has since seen increasingly widespread use. Unlike more common pseudo-first-order analysis, in which an overwhelming excess of one or more reagents is used relative to a species of interest, RPKA probes reactions at synthetically relevant conditions (i.e. with concentrations and reagent ratios resembling those used in the reaction when not exploring the rate law.) Generally, this analysis involves a system in which the concentrations of multiple reactants are changing measurably over the course of the reaction. As the mechanism can vary depending on the relative and absolute concentrations of the species involved, this approach obtains results that are much more representative of reaction behavior under commonly utilized conditions than do traditional tactics. Furthermore, information obtained by observation of the reaction over time may provide insight regarding unexpected behavior such as induction periods, catalyst deactivation, or changes in mechanism.
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