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(iii) Formation of Hydrogen chloride molecule
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... falls across the double layers at the electrode-electrolyte interfaces, which are only a few ions thick, a field close to ∼1 V/Å can be reached. The molecule chosen for this work is perylene tetracarboxylic diimide (PTCDI), a redox molecule with many unique electronic properties.9 It is also one of ...
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... bond that is reflected in a significant increase of its length (1.43 G in Figure 2 f) compared to that of the free molecule (1.25 G). Accompanying the activation process is a change in the spin state of the molecule from a triplet state in the gas phase to a peroxo-like adsorbed state with a zero ne ...
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... The Nature of Light Properties of Light • In the very beginning the experiments that would lead to the QM model of the atom began with an examination of the properties of light • So we are going to start there too. • First we will look at the wave nature of light. • The way light was first understoo ...
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Molecular orbital



In chemistry, a molecular orbital (or MO) is a mathematical function describing the wave-like behavior of an electron in a molecule. This function can be used to calculate chemical and physical properties such as the probability of finding an electron in any specific region. The term orbital was introduced by Robert S. Mulliken in 1932 as an abbreviation for one-electron orbital wave function. At an elementary level, it is used to describe the region of space in which the function has a significant amplitude. Molecular orbitals are usually constructed by combining atomic orbitals or hybrid orbitals from each atom of the molecule, or other molecular orbitals from groups of atoms. They can be quantitatively calculated using the Hartree–Fock or self-consistent field (SCF) methods.
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