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CHEM 121
CHEM 121

... Like the de Broglie relation, the Heisenberg Uncertainty Principle is important only for very small masses such as e-s, n0s, etc. §8-6 Quantum Mechanics & Schrödinger equation: Bohr model only applies to atoms with one eMotivated by classical wave equation for violin string ...
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... Electron affinity – the opposite of IE – change in energy when adding an electron 1. Across a period EA increases 2. Going down a group EA decreases Atomic radius – distance from nucleus to outermost electron 1. Across a period AR decreases Zeff 2. Going down a group AR increases A metal ion is + an ...
Chapter 1: The Basics - Bonding and Molecular Structure and
Chapter 1: The Basics - Bonding and Molecular Structure and

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Bohr Atom

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2. Many-electron systems

... The angular part of the wave functions will be the SAME, i.e. Y (ϑ, ϕ). Therefore we can again classify the orbitals as 1s, 2s, 2p0 , 2p1 , 2p−1 , etc. The radial part: R(r) will differ, since the potential is different here form that of the H atom: since it is not a simple Coulomb-potencial, the de ...
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Figure 7.18 The 3d orbitals

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ECE-301 ELECTRICAL NETWORKS I

< 1 ... 209 210 211 212 213 214 215 216 217 ... 231 >

Tight binding

In solid-state physics, the tight-binding model (or TB model) is an approach to the calculation of electronic band structure using an approximate set of wave functions based upon superposition of wave functions for isolated atoms located at each atomic site. The method is closely related to the LCAO method used in chemistry. Tight-binding models are applied to a wide variety of solids. The model gives good qualitative results in many cases and can be combined with other models that give better results where the tight-binding model fails. Though the tight-binding model is a one-electron model, the model also provides a basis for more advanced calculations like the calculation of surface states and application to various kinds of many-body problem and quasiparticle calculations.
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