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Thermodynamics: Spontaneity, Entropy and Free energy

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... yield. It runs from 0% (all reactants) to 100% (all products). This is simply more convenient than Q, which runs from 0 to infinity. The way I look at it is this for a weak acid: %ionization = [A−]eq/[HA]o x 100% That is, the “final” concentration of A− at equilibrium divided by the “initial” concen ...
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Equilibrium chemistry



Equilibrium chemistry is a concerned with systems in chemical equilibrium. The unifying principle is that the free energy of a system at equilibrium is the minimum possible, so that the slope of the free energy with respect to the reaction coordinate is zero. This principle, applied to mixtures at equilibrium provides a definition of an equilibrium constant. Applications include acid-base, host-guest, metal-complex, solubility, partition, chromatography and redox equilibria.
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