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12.3
12.3

... In this section, we introduce two different ways of expressing the concentrations of solutions: molarity and m ­ olality. Sometimes, solutions are referred to as “dilute” or “concentrated,” but these are not very definite terms. “Dilute” just means that there is a relatively small amount of solute i ...
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... by a given ion in the interior of both phases, which is exactly the electric work required to transfer this ion from the interior of one phase to the interior of the other.9,28 The potential arising from the reference electrode is by definition only a voltage shift with respect to the standard hydro ...
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A molecular dynamics study of pressure effects on solvation and

... molecule increases.I8 For liquid methanol, the application of pressures to I 5 kbar does not appear to increase the strength or number of hydrogen bonds.Ig For model solutes like formaldehyde which undergo a large change in their dipole moment and hydrogen-bonding properties upon excitation, it is u ...
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... surfactant molecules arrange themselves into organized molecular assemblies known as micelles (Fig. 1). The hydrophobic part of the aggregate forms the core of the micelle, while the polar head groups are located at the micelle–water interface in contact with and hydrated by a number of water molecu ...
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... 2. Conceptual Definitions. Acids and bases can be defined conceptually to help account for what is happening on a microscopic level. Arrhenius concept. An acid is a substance that, when dissolved in water, forms hydrogen ions (or protons, H+). A base is a substance that, when dissolved in water, for ...
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Cyclo-P3 Complexes of Vanadium: Redox

... quite unique and, to our knowledge, has been observed only for a very limited number of d8 metals, [(triphos)Ni(cycloP3)Pt(PH3)2]+1, and [Au{M(tppme)(cyclo-P3)}2]+ (M = Co, Rh, and Ir).29,30 Irrespective of this finding, it is very likely that the system is fluxional at room temperature, yielding an o ...
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...  The ingredient that makes the least amount of pizza will determine how many pizzas you can make. Let us carry this analogy one step further. Suppose we go on to cook our pizzas and accidentally burn one of them. So even though we theoretically have enough ingredients for 3 pizzas, we end up with o ...
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Equilibrium chemistry



Equilibrium chemistry is a concerned with systems in chemical equilibrium. The unifying principle is that the free energy of a system at equilibrium is the minimum possible, so that the slope of the free energy with respect to the reaction coordinate is zero. This principle, applied to mixtures at equilibrium provides a definition of an equilibrium constant. Applications include acid-base, host-guest, metal-complex, solubility, partition, chromatography and redox equilibria.
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