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Exam 1 Key
Exam 1 Key

... ΔG is positive even when the entropy is increasing. Thus, ΔH has to be a large positive number in order for ΔG to be positive. 25. Calculate the standard enthalpy of reaction for the reaction: NO2 (g) → NO (g) + O (g) Given the following reactions and their standard enthalpy changes: (7 pts) ...
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... with time but also need to have no change with removal of the system from contact with its surroundings ◦ If removal of the system does change the macroscopic properties, it is in a steady state • Mechanical Equilibrium: No unbalanced forces act on or within the system • Material Equilibrium: No net ...
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Equilibrium chemistry



Equilibrium chemistry is a concerned with systems in chemical equilibrium. The unifying principle is that the free energy of a system at equilibrium is the minimum possible, so that the slope of the free energy with respect to the reaction coordinate is zero. This principle, applied to mixtures at equilibrium provides a definition of an equilibrium constant. Applications include acid-base, host-guest, metal-complex, solubility, partition, chromatography and redox equilibria.
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