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([Cu(NH3)4](MnO4)2)

Chapter 14: Chemical Kinetics
Chapter 14: Chemical Kinetics

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... Analyze: We are given a volume and initial molar amounts of the species in a reaction and asked to determine in which direction the reaction must proceed to achieve equilibrium. Plan: We can determine the starting concentration of each species in the reaction mixture. We can then substitute the star ...
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... The advantage of this definition is that it allows us to perceive the equilibrium constant Kc as the ratio of the rate constants. Importantly, the Equilibrium Law expresses Kc as a relationship between the concentrations of products and reactants in a system at equilibrium, and it provides us with a ...
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... Limiting and Excess Reagents • In a chemical reaction, an insufficient quantity of any of the reactants will limit the amount of product formed. – Limiting reagent is the reactant that determines the amount of product that can be formed by a reaction – Excess reagent is the reactant that is not com ...
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Chemical Reactions

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Organic Chemistry II

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NICKEL(II) PINCER COMPLEXES SUPPORTED BY 2,6

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... and NCS−(aq) ions (making the denominator bigger). Thus, although both forward and reverse reactions occur simultaneously, the reverse reaction will predominate to decrease the Fe(NCS)2+(aq) concentration until equilibrium is established. When the reverse reaction occurs to a greater extent than the ...
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Topic 3: Chemical Kinetics - Manitoba Education and Training

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GCE Getting Started - Edexcel

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... Factors Affecting Reaction Rate: Nature of the Reactants • Nature of the reactants means what kind of reactant molecules and what physical condition they are in  small molecules tend to react faster than large molecules  gases tend to react faster than liquids, which react faster than solids  po ...
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Document

... Factors Affecting Reaction Rate: Nature of the Reactants • Nature of the reactants means what kind of reactant molecules and what physical condition they are in  small molecules tend to react faster than large molecules  gases tend to react faster than liquids, which react faster than solids  po ...
Chapter
Chapter

< 1 ... 5 6 7 8 9 10 11 12 13 ... 53 >

Supramolecular catalysis



Supramolecular catalysis is not a well-defined field but it generally refers to an application of supramolecular chemistry, especially molecular recognition and guest binding, toward catalysis. This field was originally inspired by enzymatic system which, unlike classical organic chemistry reactions, utilizes non-covalent interactions such as hydrogen bonding, cation-pi interaction, and hydrophobic forces to dramatically accelerate rate of reaction and/or allow highly selective reactions to occur. Because enzymes are structurally complex and difficult to modify, supramolecular catalysts offer a simpler model for studying factors involved in catalytic efficiency of the enzyme. Another goal that motivates this field is the development of efficient and practical catalysts that may or may not have an enzyme equivalent in nature.A closely related field of study is asymmetric catalysis which requires molecular recognition to differentiate two chiral starting material or chiral transition states and thus it could be categorized as an area of supramolecular catalysis, but supramolecular catalysis however does not necessarily have to involve asymmetric reaction. As there is another Wikipedia article already written about small molecule asymmetric catalysts, this article focuses primarily on large catalytic host molecules. Non-discrete and structurally poorly defined system such as micelle and dendrimers are not included.
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