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ENZYMES
ENZYMES

Chemical Synthesis Using Earth-Abundant Metal
Chemical Synthesis Using Earth-Abundant Metal

(Cyclophane family) and Derivatives as Supramolecular Scaffolds‌
(Cyclophane family) and Derivatives as Supramolecular Scaffolds‌

anna-chrobok-silesian-university-of-technology
anna-chrobok-silesian-university-of-technology

Viju B - IS MU
Viju B - IS MU

Catalysis
Catalysis

... 4. Enzyme catalysed reactions are much more sensitive to catalytic poisons such as HCN, H2S, CS2 etc. The inhibitors interact with the active functional groups present on the enzyme surface and often reduce or completely destroy the catalytic activity of the enzymes 5. The activity of certain enzym ...
Enzymes
Enzymes

Main article: Heterogeneous catalysis
Main article: Heterogeneous catalysis

... leads to a net reaction of one Mol per second of the reactants to the resulting reagents or other outcome which was intended for this chemical reaction. A catalyst may and usually will have different catalytic activity for several distinct reactions. See katal for an example. There are further deriv ...
Chemical Reactions and Enzymes What is a chemical reaction?
Chemical Reactions and Enzymes What is a chemical reaction?

CELSA - Collaborative research project - Application form
CELSA - Collaborative research project - Application form

... Complex pharmaceuticals often have the desired medical effect only in one ‘enantiomeric’ form, while the mirror image may have no or even adverse effects. Biocatalysts like enzymes often succeed to transform selectively 1 of the 2 enantiomers of a precursor to a desired product, a process termed ‘Ki ...
Reactions
Reactions

Organometallic Compounds and Catalysis: Synthesis
Organometallic Compounds and Catalysis: Synthesis

KEY CONCEPT Enzymes are catalysts for chemical
KEY CONCEPT Enzymes are catalysts for chemical

... – Enzymes are needed for almost all processes. – Most enzymes are proteins. ...
Title - Iowa State University
Title - Iowa State University

Switchable nanocatalysts: using ferroelectric oxides to control surface catalysis
Switchable nanocatalysts: using ferroelectric oxides to control surface catalysis

< 1 ... 49 50 51 52 53

Supramolecular catalysis



Supramolecular catalysis is not a well-defined field but it generally refers to an application of supramolecular chemistry, especially molecular recognition and guest binding, toward catalysis. This field was originally inspired by enzymatic system which, unlike classical organic chemistry reactions, utilizes non-covalent interactions such as hydrogen bonding, cation-pi interaction, and hydrophobic forces to dramatically accelerate rate of reaction and/or allow highly selective reactions to occur. Because enzymes are structurally complex and difficult to modify, supramolecular catalysts offer a simpler model for studying factors involved in catalytic efficiency of the enzyme. Another goal that motivates this field is the development of efficient and practical catalysts that may or may not have an enzyme equivalent in nature.A closely related field of study is asymmetric catalysis which requires molecular recognition to differentiate two chiral starting material or chiral transition states and thus it could be categorized as an area of supramolecular catalysis, but supramolecular catalysis however does not necessarily have to involve asymmetric reaction. As there is another Wikipedia article already written about small molecule asymmetric catalysts, this article focuses primarily on large catalytic host molecules. Non-discrete and structurally poorly defined system such as micelle and dendrimers are not included.
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