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Hydrothermal Reactions from Sodium Hydrogen Carbonate to Phenol
Hydrothermal Reactions from Sodium Hydrogen Carbonate to Phenol

Chapter 4:Chemical Quantities and Aqueous Reactions:
Chapter 4:Chemical Quantities and Aqueous Reactions:

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Physical Science Chapter 7 Chemical Reactions Section 7.1

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... also made it possible to study nanoparticle catalysis at the singleparticle level. Electrochemical measurements,27-33 electrogenerated chemiluminescence,34 surface plasmon resonance,35 and fluorescence microscopy36-40 have been used to detect catalytic reactions of individual nanoparticles. By remov ...
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Topic guide 9.3: Drug discovery and design

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Inorganic Chemistry 412 / 512

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Chemical Reactions: Helpful Hints

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Packet #7- Chemical Reactions

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Chapter 5—Chemical Reactions

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Supramolecular catalysis



Supramolecular catalysis is not a well-defined field but it generally refers to an application of supramolecular chemistry, especially molecular recognition and guest binding, toward catalysis. This field was originally inspired by enzymatic system which, unlike classical organic chemistry reactions, utilizes non-covalent interactions such as hydrogen bonding, cation-pi interaction, and hydrophobic forces to dramatically accelerate rate of reaction and/or allow highly selective reactions to occur. Because enzymes are structurally complex and difficult to modify, supramolecular catalysts offer a simpler model for studying factors involved in catalytic efficiency of the enzyme. Another goal that motivates this field is the development of efficient and practical catalysts that may or may not have an enzyme equivalent in nature.A closely related field of study is asymmetric catalysis which requires molecular recognition to differentiate two chiral starting material or chiral transition states and thus it could be categorized as an area of supramolecular catalysis, but supramolecular catalysis however does not necessarily have to involve asymmetric reaction. As there is another Wikipedia article already written about small molecule asymmetric catalysts, this article focuses primarily on large catalytic host molecules. Non-discrete and structurally poorly defined system such as micelle and dendrimers are not included.
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