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Activities From Freezing-Point Depression Data1,2 Purpose
Activities From Freezing-Point Depression Data1,2 Purpose

... The water is drained off and replaced by 100-mL of the chilled 3.0 m solution of 2-propanol prepared above. The solution and ice are stirred vigorously until a constant temperature is reached, whereupon the temperature is recorded and a sample is withdrawn quickly with a 10-ml pipette; the tip of th ...
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... __PHYSICAL__ properties can be observed without chemically changing matter. ___CHEMICAL_____ properties describe how a substance interacts with other substances. __SOLIDS___ have definite shapes and definite volumes. __LIQUIDS_____ have indefinite shapes and definite volumes. ___GASES/ PLASMA______ ...
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... thermoelectric materials began when Slack theorized the so-called “electron crystals-phonon glass”[1]. Slack considered that a good TE material should have the electronic structure of a heavily doped narrow-band-gap semiconductor and thermal conductivity like a glass. One of new class materials for ...
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... exothermic event approximately at 55ºC overlapping the glass transition temperature. These thermograms are completely different to amorphous samples (Figure 1). The new exothermic event is only showed in milled samples. Both milling times present the sample this event being more prominent at 30 min. ...
Thermodynamics and Kinetics of Solids 21 ________________________________________________________________________________________________________________________
Thermodynamics and Kinetics of Solids 21 ________________________________________________________________________________________________________________________

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Glass transition



The glass–liquid transition or glass transition for short is the reversible transition in amorphous materials (or in amorphous regions within semicrystalline materials) from a hard and relatively brittle state into a molten or rubber-like state. An amorphous solid that exhibits a glass transition is called a glass. Supercooling a viscous liquid into the glass state is called vitrification, from the Latin vitreum, ""glass"" via French vitrifier.Despite the massive change in the physical properties of a material through its glass transition, the transition is not itself a phase transition of any kind; rather it is a laboratory phenomenon extending over a range of temperature and defined by one of several conventions. Such conventions include a constant cooling rate (20 K/min) and a viscosity threshold of 1012 Pa·s, among others. Upon cooling or heating through this glass-transition range, the material also exhibits a smooth step in the thermal-expansion coefficient and in the specific heat, with the location of these effects again being dependent on the history of the material. However, the question of whether some phase transition underlies the glass transition is a matter of continuing research.The glass-transition temperature Tg is always lower than the melting temperature, Tm, of the crystalline state of the material, if one exists.
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