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ap chemistry syllabus - West Essex High School
ap chemistry syllabus - West Essex High School

... Be familiar with how the internal energy of a system is affected by exchanges of heat and work between the system and the surroundings. Understand what a state function is. Define enthalpy, and explain how heat transfer from or to the system at constant pressure changes it. Know what the sign of the ...
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Glossary - WordPress.com

... When two typical salts are crystallized together a double salt is formed. The physical properties of the crystals of double salt are different from those of the component salts. Doberiner’s Law of Triads ...
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... 12 When EDTA is added to [Cu(NH3)4]2+ in aqueous solution, the copper(II)-EDTA complex, [Cu(EDTA)]2–, predominates in the resulting solution. This is best explained by the fact that when [Cu(EDTA)]2– is formed from [Cu(NH3)4]2+ A there are much stronger bonds between the ligands and the copper(II) i ...
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... b. The solution shows a positive deviation from Raoult’s Law. c. The solution shows a negative deviation from Raoult’s Law and possesses a minimum boiling point azeotrope. d. The solution shows a negative deviation from Raoult’s Law and possesses a maximum boiling point azeorope. e. The solution pro ...
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... This compound was prepared from the nitrate salt, which was prepared according to the literature methodZ3 with the following modification. Concentrated aqueous ammonia was added slowly dropwise to a solution of HAuCI4 3 H 2 0 that was nearly saturated with N H 4 N 0 3 . The pH was never allowed to g ...
OXIDATION - REDUCTION
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Chemical Equilbrium
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... assumption, many times you will end up with a quadratic equation for an equilibrium constant expression. You can end up with a 3rd, 4th, 5th, etc. order polynomial, but I will not hold you responsible for being able to solve those as there is no simple formula for the solution. ...
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... 1. The VSEPR model for predicting structure generally does not work for complex ions.  However, assume a complex ion with a coordination number of 6 will have an octahedral arrangement of ligands.  And, assume complexes with two ligands will be linear.  But, complexes with a coordination number o ...
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... The quantum yields of nickel and palladium complexes decrease with increasing irradiation wavelength. However, no significant dependence was observed in the case of the platinum complexes. Upon irradiation with visible light (A,,<350 nm) the LMCT band disappears due to the oxidation of the azide lig ...
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Stability constants of complexes

A stability constant (formation constant, binding constant) is an equilibrium constant for the formation of a complex in solution. It is a measure of the strength of the interaction between the reagents that come together to form the complex. There are two main kinds of complex: compounds formed by the interaction of a metal ion with a ligand and supramolecular complexes, such as host-guest complexes and complexes of anions. The stability constant(s) provide the information required to calculate the concentration(s) of the complex(es) in solution. There are many areas of application in chemistry, biology and medicine.
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