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lecture_notes_5
lecture_notes_5

... c. Consider these two compounds that can be formed from carbon and oxygen: CO and CO2. d. Using the word “carbon oxide” would not be sufficient, because tere are two different forms of “carbon oxide.” e. Because carbon is not an ion in these compounds, it does not have a charge. That is one way to ...
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... Write chemical formulas for the following molecular compounds: (a) carbon disulfide (b) disilicon hexabromide ...
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... number of ways and it is therefore literally impossible to catalog all the possible heats of reaction. To get around this problem we define for each substance a standard reaction and tabulate its associated heat of reaction. These reactions and their associated heats of reaction can then be used to ...
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... use common nomenclature in transition metal chemistry. count valence electrons and determine metal oxidation state in transition metal complexes. Understand the physical basis of the 18-electron rule. appreciate the synergic nature of bonding in metal carbonyl complexes. understand the relationship ...
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introduction into Analytical Chemistry

Acids and Bases Intr.. - hrsbstaff.ednet.ns.ca
Acids and Bases Intr.. - hrsbstaff.ednet.ns.ca

... Substances that can act like an acid in one reaction, and like a base in another type of reaction. • Example: baking soda’s anion HCO31. HCO3- + OH- < -- > CO3-2 + H2O (donates a H+, so acts like an acid) 2. HCO3- + H3O+ < -- > H2CO3 + H2O (accepts a H+, so acts like a base) ...
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Chemistry@YIA – additional information

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Laboratory Exercises in Physical Chemistry

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chapter 13 - Humble ISD
chapter 13 - Humble ISD

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The Oxidation Potential of Oxygen and Chlorine Dioxide

... stomach) is neutral or even slightly basic. Eg. pH of blood and many other body fluids is maintained within a very narrow range of pH, around 7.40 (from 7.31 to 7.42). Therefore, in fields such as hydrochemistry, geochemistry and biochemistry, it is useful to convert standard potentials to pH = 7. T ...
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What is Thermodynamics?

... • A negative value (exothermic reaction) means that the products of reaction have less enthalpy than the sum of the reactants and that heat is released to the surroundings when the reaction occurs in the forward direction. • Exothermic reactions don’t require the addition of heat energy from their ...
Group 7 - Plantsbrook Science
Group 7 - Plantsbrook Science

Document
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... Writing Equilibrium Constant Expressions 1. The concentrations of the reacting species in the condensed phase are expressed in M. In the gaseous phase, the concentrations can be expressed in M or in atm. 2. The concentrations of pure solids, pure liquids and solvents do not appear in the equilibriu ...
chemical reactions and energy changes
chemical reactions and energy changes

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Use of the Jahn-Teller Theorem in Inorganic Chemistry

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Metal to Ligand and Ligand to Metal Charge Transfer

... CT  absorptions  are  selection  rule  allowed  and  result  in  intense  (ε  values  of  50,000  L  mole­1  cm­1  or  greater)  bands  in  the  UV/Vis region.2Selection rule forbidden d­d transitions result in weak absorptions. For example octahedral complexes give ε values of 20 L mol­ 1 cm­1 or l ...
Lecture 1: RDCH 710 Introduction
Lecture 1: RDCH 710 Introduction

... * Lanthanide 4f occupy inner orbits that are not accessable • Basis for chemical differences between lanthanides and actinides ...
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title of abstract

... series of samarium standard solutions and from the slope of corresponding calibration curve the molar extinction coefficient  of the Sm(III)-arsenazo at 650 nm was determined,  = (27000 ± 1000) (l mol-1 cm-1). All measurements were repeated and the error bars in the graphs correspond to the standa ...
Ksp - ChemConnections
Ksp - ChemConnections

... Zn2+, Mn2+, Ni2+, Fe2+, Co2+ as sulfides, and Al3+, Cr3+ as hydroxides ...
Acid Base Equilibrium
Acid Base Equilibrium

... We can categorize acids and bases according to their behavior in water. • 1. Strong acids completely transfer their protons to water. • No undissociated molecules remain in solution. • Their conjugate bases have negligible tendencies to become protonated. • An example is HCl. • 2. Weak acids only pa ...
Density Functional Study of Electronic, Magnetic and Hyperfine
Density Functional Study of Electronic, Magnetic and Hyperfine

... in the diamagnetic complexes have shown that the outer unpaired electron occupies an orbital almost entirely localized on the Fe-N-O (or Ru-N-O) group of atoms. Therefore, rather than optimizing the structural parameters of the complete complexes (which was not the scope of the present study), only ...
Class notes - Bullis Haiku
Class notes - Bullis Haiku

... Suppose you want to identify WHICH ions precipitate out of solution in the first 4 groups or are left in solution (Group V). We can actually identify which ions are present based on the solubility of the complex ions. I will show you how you can identify which ions are present in the Group I precipi ...
NCEA Level 1 Chemistry (90933) 2014
NCEA Level 1 Chemistry (90933) 2014

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Stability constants of complexes

A stability constant (formation constant, binding constant) is an equilibrium constant for the formation of a complex in solution. It is a measure of the strength of the interaction between the reagents that come together to form the complex. There are two main kinds of complex: compounds formed by the interaction of a metal ion with a ligand and supramolecular complexes, such as host-guest complexes and complexes of anions. The stability constant(s) provide the information required to calculate the concentration(s) of the complex(es) in solution. There are many areas of application in chemistry, biology and medicine.
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