Thesis - Max Planck Institut für Festkörperforschung
... covalent bonds, their benefit lies in their flexibility and reversibility. Annealing can heal structural errors to obtain thermodynamic equilibrium. One of the most widely used strategies to build up supramolecular architectures is based on the coordination of metal atoms with organic ligands [27, 2 ...
... covalent bonds, their benefit lies in their flexibility and reversibility. Annealing can heal structural errors to obtain thermodynamic equilibrium. One of the most widely used strategies to build up supramolecular architectures is based on the coordination of metal atoms with organic ligands [27, 2 ...
Synthetically Important AlkaliMetal Utility Amides: Lithium, Sodium
... LDA or KHMDS for the deprotonation of weakly acidic compounds. Sauer first described hexamethyldisilazane in 1944 as a precursor to trimethylsilanol and obtained by ammonolysis of trimethylchlorosilane.[19] The alkali-metal HMDS complexes were subsequently described by Wannagat and Niederprm, first ...
... LDA or KHMDS for the deprotonation of weakly acidic compounds. Sauer first described hexamethyldisilazane in 1944 as a precursor to trimethylsilanol and obtained by ammonolysis of trimethylchlorosilane.[19] The alkali-metal HMDS complexes were subsequently described by Wannagat and Niederprm, first ...
Effects of Electrolyte Concentration and pH on
... centrifugation was appropriately modified to measure PCR OSM, which can be used as a convenient quantitative measure of the emulsion coalescence stability.14,15 In parallel experiments, protein adsorption on the surface of the emulsion drops was determined. The results demonstrated14,15 that PCR OSM ...
... centrifugation was appropriately modified to measure PCR OSM, which can be used as a convenient quantitative measure of the emulsion coalescence stability.14,15 In parallel experiments, protein adsorption on the surface of the emulsion drops was determined. The results demonstrated14,15 that PCR OSM ...
Late Transition Metal Amido Complexes: Electronic
... series of group 9 and 10 (d6 and d8) complexes with the chelating disilylamido PNP pincer ligand N(SiMe2CH2PR2)2.[13] A proton transfer to the amido ligand result upon H2 heterolysis ...
... series of group 9 and 10 (d6 and d8) complexes with the chelating disilylamido PNP pincer ligand N(SiMe2CH2PR2)2.[13] A proton transfer to the amido ligand result upon H2 heterolysis ...
Document
... Strategy Look up standard enthalpy values and calculate ΔS°rxn. Just as we did when we calculated standard enthalpies of reaction, we consider stoichiometric coefficients to be dimensionless–giving ΔS°rxn units of J/K∙mol. From Appendix 2, S°[CaCO3(s)] = 92.9 J/K∙mol, S°[CaO(s)] = 39.8 J/K∙mol, S°[C ...
... Strategy Look up standard enthalpy values and calculate ΔS°rxn. Just as we did when we calculated standard enthalpies of reaction, we consider stoichiometric coefficients to be dimensionless–giving ΔS°rxn units of J/K∙mol. From Appendix 2, S°[CaCO3(s)] = 92.9 J/K∙mol, S°[CaO(s)] = 39.8 J/K∙mol, S°[C ...
Chapter 4 Chemical Quantities and Aqueous Reactions
... • so to describe solutions accurately, we must describe how much of each component is present we saw that with pure substances, we can describe them with a single name because all samples identical Tro, Chemistry: A Molecular Approach ...
... • so to describe solutions accurately, we must describe how much of each component is present we saw that with pure substances, we can describe them with a single name because all samples identical Tro, Chemistry: A Molecular Approach ...
III. Polyelectrolyte Phenomena (Dautzenberg et al., Polyelectrolytes
... which the polyelectrolyte coils overlap and perhaps entangle with one another. Unfortunately, many of the properties of semidilute and concentrated polyelectrolyte solutions are not well understood. The crossover from dilute to semidilute occurs at a value of c termed the critical overlap concentrat ...
... which the polyelectrolyte coils overlap and perhaps entangle with one another. Unfortunately, many of the properties of semidilute and concentrated polyelectrolyte solutions are not well understood. The crossover from dilute to semidilute occurs at a value of c termed the critical overlap concentrat ...
Document
... • so to describe solutions accurately, we must describe how much of each component is present we saw that with pure substances, we can describe them with a single name because all samples identical Tro, Chemistry: A Molecular Approach ...
... • so to describe solutions accurately, we must describe how much of each component is present we saw that with pure substances, we can describe them with a single name because all samples identical Tro, Chemistry: A Molecular Approach ...
Matti Kaisti – Field-effect based chemical and biological sensing
... field-effect transistor (FET) based sensors, the transducing principle relies on direct detection of interfacial charge allowing detection of various ions and charged macromolecules. This thesis investigates FET based sensors for biological and chemical sensing. First, an ion-sensitive floating gate ...
... field-effect transistor (FET) based sensors, the transducing principle relies on direct detection of interfacial charge allowing detection of various ions and charged macromolecules. This thesis investigates FET based sensors for biological and chemical sensing. First, an ion-sensitive floating gate ...
Counting the Number of Magnesium Ions Bound to the Surface
... phosphate group along the DNA backbone without blocking the base sites that are required for hybridization.27−29 Additionally, the presence of magnesium is well-known to stabilize DNA duplexes in solution.28,30−33 Melting temperature (Tm) increases have been observed until Mg2+ concentrations of 10− ...
... phosphate group along the DNA backbone without blocking the base sites that are required for hybridization.27−29 Additionally, the presence of magnesium is well-known to stabilize DNA duplexes in solution.28,30−33 Melting temperature (Tm) increases have been observed until Mg2+ concentrations of 10− ...
Fouks_Jordan_Phosvitin
... peptides, peptides complexed with ions, or other phenomena. This analysis is complicated by the potential ion binding nature of these phosphopeptides. Clusters of ions, like calcium, complicate the interpretation of what are noted here as potential multiply phosphorylated peptides. Trypsin hyd ...
... peptides, peptides complexed with ions, or other phenomena. This analysis is complicated by the potential ion binding nature of these phosphopeptides. Clusters of ions, like calcium, complicate the interpretation of what are noted here as potential multiply phosphorylated peptides. Trypsin hyd ...
