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Organic synthesis
Organic synthesis

... heat will prevent crystals reforming during filtration ...
Honors Biology - LangdonBiology.org
Honors Biology - LangdonBiology.org

... is in the middle P slot. The tRNA that reads this codon, and carries the amino acid methionine, slides into the P slot and the anticodon and codon bases hydrogen bond. The second codon is under the A slot. The second tRNA that reads the second codon slides in. This puts the two amino acids, methioni ...
Elias lecture chemistry of chlorine 2016 nov
Elias lecture chemistry of chlorine 2016 nov

... On dilution in water, however, a cloudy liquid forms. This consists of droplets of pine oil containing dissolved PCMX. These are held dispersed in water by a layer of soap molecules arranged with their tails in the pine oil and their heads in the water, Figure 13. These droplets are big enough to sc ...
esterification of palmitic acid with methanol in the
esterification of palmitic acid with methanol in the

Synthesis of Several Esters
Synthesis of Several Esters

Aldehydes and Ketones
Aldehydes and Ketones

Level 3 Chemistry (91391) 2013
Level 3 Chemistry (91391) 2013

... (ii) Link the structure of enantiomers to a physical property that can be used to distinguish them from non-optically active molecules. ...
Chapter Seventeen
Chapter Seventeen

Organic Chemistry Fifth Edition
Organic Chemistry Fifth Edition

... enamine. hydrazone. imine. ...
cellulose
cellulose

... alcohols, as model compounds, has congroups in cellulose suggests that any resisrlI1I1ed that the ring formation during silylatance to sHylation may be due mostly to tion of cellulose with dichlorodisiloxane is steric reasons and lack of solubility than to uncertain. intrinsic chemical difficulties ...
Experiment # 8 Synthesis and Reactivity of tert
Experiment # 8 Synthesis and Reactivity of tert

Amines
Amines

... principle in the smell of rotting fish  two other particularly pungent amines are 1,4-butanediamine (putrescine) and 1,5pentanediamine (cadaverine) ...
IUPAC nomenclature for organic chemistry
IUPAC nomenclature for organic chemistry

... Naming Amines • Primary Amines (R-NH2): • Replace the –e of the parent group with the word amine • Can also name it as a substituent using the name amino ...
Amino acids
Amino acids

... • The nonpolar R-group fill up the interior of the folded protein and help give it its 3D shape. ...
New process of low-temperature methanol synthesis from CO/CO2
New process of low-temperature methanol synthesis from CO/CO2

... listed in table 1. From table 1, no activity appears when cyclohexane is used as solvent or ethanol used as solvent but no catalyst is used. However, when cyclohexanol is used instead of cyclohexane, methanol is the only product and its yield arrives at 6.18% after 2 h reaction. Benzyl alcohol and e ...
macromolecule foldable
macromolecule foldable

... FRONT SIDE OF TABS: Tab A 1. Label the tab PROTEIN 2. To the left write “monomer:” and fill in the name for the monomer for proteins. 3. Under “monomer:” write “polymer:” and fill in the name for the polymer for proteins. 4. Sketch and color an AMINO ACID TAB B 1. Label the tab CARBOHYDRATE 2. To th ...
File - the prayas tutorial
File - the prayas tutorial

... Q. 6. Grignard reagents should be prepared under anhydrous conditions. Why ? Ans. Because Grignard reagents have a very strong affinity for H+ ions. In presence of water, they abstract H+ ions from water and form alkanes. To prevent this, they should be prepared under anhydrous conditions. Q. 7. Hal ...
Get Solutions - Iqraa group of institutes
Get Solutions - Iqraa group of institutes

... here ZnO acts as an base ZnO is an amphoteric oxide but in given reaction. 25. The radius of the second Bohr orbit for hydrogen atom is : (Planck’s Const. H= 6.6262×10-34 Js; mass of electr0n=9.1091×10-31 kg; charge of electron e = 1.60210×10-19 C; permittivity of vacuum ...
Practice Exam 3 Key
Practice Exam 3 Key

... 24. (4 pts.) Rank the following compounds (that have similar mass) h order of decreasing solubility in pentane: the primary amine pentyl a e (C5HI3N), he (C6HI4), et yl propyl ether (C5HI20), and butanoic acid (C4H8O2). ...
PDF w - Erowid
PDF w - Erowid

Chapter 22/23-Organic Chemistry
Chapter 22/23-Organic Chemistry

... 2. Draw the following Organic compounds: a. 2-bromopentanoic acid b. 1, 3-pentanediol c. 10-chloro-1-decanol d. 2,3,4,5-tetrachlorohexanal e. 2-chloro-6-methylheptanoic acid f. ethyl 3,4-dimethylhexanoate g. 4-methylpentyl-3-chlorohexanoate h. 2-bromo-6-phenyl-3cyclopropyl-7-nonanone ...
Highly Enantioselective Cyclocarbonylation of Allylic
Highly Enantioselective Cyclocarbonylation of Allylic

... chiral γ-butyrolactones 4 in good to excellent enantioselectivities (up to 98% ee) (Table 2). In general, introduction of aromatic substituents at the β or γ position of allylic alcohols enhances the enantioselectivity (entries 1-6 vs entry 7). The lactonization of the allylic alcohols 3 likely proc ...
AROMATIC COMPOUNDS
AROMATIC COMPOUNDS

... Friedel–Crafts alkylation will not produce a good yield of an alkylbenzene containing a straight-chain group, because the carbocation will rearrange: ...
Concise Synthesis of (ю)-allo-Kainic Acid via MgI 2‑Mediated
Concise Synthesis of (ю)-allo-Kainic Acid via MgI 2‑Mediated

... the Michael acceptor was not reactive enough to undergo the addition process.15 We reasoned that the use of a more activating group such as a thioester or an oxazolidinone would promote the initial nucleophilic attack. Pleasingly, when thioester 4c was used, the reaction gave a mixture of diastereoi ...
ppt
ppt

... the O-H group of alcohols act as both an H-bond donor (Lewis acid) and H-bond acceptor (Lewis base). Ethers are only H-bond acceptors (Lewis base) 16.4: Crown Ethers (Please read) ...
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Petasis reaction



The Petasis reaction (alternatively called the Petasis borono–Mannich (PBM) reaction) is the chemical reaction of an amine, aldehyde, and vinyl- or aryl-boronic acid to form substituted amines.Reported in 1993 by Nicos Petasis as a practical method towards the synthesis of a geometrically pure antifungal agent, naftifine, the Petasis reaction can be described as a variation of the Mannich reaction. Rather than generating an enolate to form the substituted amine product, in the Petasis reaction, the vinyl group of the organoboronic acid serves as the nucleophile. In comparison to other methods of generating allyl amines, the Petasis reaction tolerates a multifunctional scaffold, with a variety of amines and organoboronic acids as potential starting materials. Additionally, the reaction does not require anhydrous or inert conditions. As a mild, selective synthesis, the Petasis reaction is useful in generating α-amino acids, and is utilized in combinatorial chemistry and drug discovery.
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