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Properties_problems 5
Properties_problems 5

... saturated liquid to the ideal gas state at infinite dilution and Vi is the molar volume of the liquid. The solubility parameter of a polymer has to be determined indirectly or calculated by group-contribution methods. Calculation of  by a group-contribution method requires the value of a molar att ...
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Document

... 1. In the reaction 2 H2(g) + O2(g) → 2 H2O(l), 3 mol of gas-phase molecules is replaced by 2 mol of liquid-phase molecules, so ∆ng = −3 mol. Therefore, at 298 K, when RT = 2.5 kJ mol−1, the enthalpy and internal energy changes taking place in the system are related by • Note that the difference is e ...
FLUID-SOLID SEPARATION_Adsorption
FLUID-SOLID SEPARATION_Adsorption

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Experiment 1

... The experimental variable that appears in equations (1), (3), and (4) in the preceding discussion is not the freezing point of a solution but the freezing point depression: the difference between the freezing point of the solution and the freezing point of pure water (calculated as a positive differ ...
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Answer Key

The applicability of activities in kinetic expressions Haubrock, J.
The applicability of activities in kinetic expressions Haubrock, J.

... solution. The horizontal gas–liquid contact area in the reactor was determined to be 71.5 cm2 . The gas supply vessel had a volume of 100 ml and the pressure in that vessel at the start of an experiment was close to 5 bar. The experimental procedure for a batch experiment was as follows: a freshly p ...
1 SOLUTIONS
1 SOLUTIONS

Aquo complexes of simple Cu+, Ag+ and Aut ions and the acidities
Aquo complexes of simple Cu+, Ag+ and Aut ions and the acidities

Synthesis, characterization of some transition metal
Synthesis, characterization of some transition metal

... corresponding to d value 2.98Å.The diffractogram of Zn(II) complex of L shows twenty one reflections with maxima at 2θ = 4.14° corresponding to d value 10.65Å. The x-ray diffraction pattern of these complexes with respect to major peaks of relative intensity greater than 10% has been indexed by usin ...
PDF
PDF

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Document

... • At equilibrium, Q = K, and DG = 0. • The equation becomes 0 = DG° + RT ln K • Rearranging, this becomes DG° = RT ln K or DG/RT K=e ...
Leaching of Sphalerite with Hydrogen Peroxide and Nitric Acid
Leaching of Sphalerite with Hydrogen Peroxide and Nitric Acid

... method of Levespiel [12]. From the analysis equation (10) gave straight lines, which could be concluded that the leaching process is chemical control. The rate constant, k of the reaction were determined and plotted against 1/T shown figure 6. The slope of this plot was used to determine the apparen ...
CHEM 113 GENERAL CHEMISTRY LABORATORY
CHEM 113 GENERAL CHEMISTRY LABORATORY

... lab coat and students without lab coat will not be allowed in the lab. 2. Safety glasses must be worn at all times when in the laboratory! All students have to wear safety glasses in the lab and students without safety glasses will not be allowed in the lab. Contact lenses are not allowed in the lab ...
Equation Writing Information
Equation Writing Information

Introduction to Qualitative Analysis
Introduction to Qualitative Analysis

Estimate the strength of given sodium carbonate solution
Estimate the strength of given sodium carbonate solution

... compound of sufficient purity from which a standard solution can be prepared by directly weighing of a quantity of it, followed by dilution to give a defined volume of solution. A primary standard solution must follow these conditions:  Compound should be free from impurity.  Compound should be co ...
chem A exercise package C
chem A exercise package C

... electron into this overlapping region or into an electron "pool." By doing this, each atom appears to gain an electron within its original boundary. For every overlapping region an atom appears to gain one electron. Two overlapping regions, such as for oxygen, will result in the gain of two electron ...
Introduction to corrosion
Introduction to corrosion

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Slide 1 - scie

... SPECIFICATIONS ...
Thermochemical Investigations of Nearly Ideal
Thermochemical Investigations of Nearly Ideal

... Pure Solvents at 25 "C ...
Solution Chemistry and the Hydrosphere
Solution Chemistry and the Hydrosphere

Analysis of selected gaseous organic micro
Analysis of selected gaseous organic micro

... For accurate analysis, temperature and humidity of sampled gases should be measured. Once this is the case analyte concentration determination can be based on comparison of GC peak areas for the sample and for the standard gaseous mixture. With use of the apparatus shown in figure 1 the temperature ...
2015 Unit1 Part3.2 Equilibrium2
2015 Unit1 Part3.2 Equilibrium2

... The shorthand H+(aq) is always used in stoichiometric and equilibrium equations, although this is not strictly accurate. In 1923 the new discoveries led two chemists, Brønsted and Lowry, to define acids and bases in a different way: An acid is any substance capable of donating a proton. A base ...
Acids and Bases - Hobbs High School
Acids and Bases - Hobbs High School

Hydrocarbon ions in fuel-rich, CH4-C2H2-0, flames
Hydrocarbon ions in fuel-rich, CH4-C2H2-0, flames

... detail, attachment to 0, appears to be well-described by this mechanism, while that to NO is not. This has been explained (30) in terms of the great difference in the lifetimes of the resonant states, (X-)*; that for (0,-)* is sufficiently long to allow the reaction to be viewed as taking place thro ...
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Equilibrium chemistry



Equilibrium chemistry is a concerned with systems in chemical equilibrium. The unifying principle is that the free energy of a system at equilibrium is the minimum possible, so that the slope of the free energy with respect to the reaction coordinate is zero. This principle, applied to mixtures at equilibrium provides a definition of an equilibrium constant. Applications include acid-base, host-guest, metal-complex, solubility, partition, chromatography and redox equilibria.
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