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Chemical Equations and Reactions
Chemical Equations and Reactions

... Hg (mercury) can exist by itself...but, oxygen will need to bond with another oxygen to make O2 (diatomic) To balance the atoms we need to: Put the coefficient of 2 in front of reactant HgO. Put the coefficient of 2 in front the product Hg. ...
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... Kinetic Models: The simplest model to account for reaction kinetics is the collision model. ● Molecules must collide to react ● Collision kinetic energy supplies potential energy that the reactants need to form products. ● Activation energy (Ea): is a threshold energy necessary for the reaction to o ...
Chemistry Review: Unit2 - Menno Simons Christian School
Chemistry Review: Unit2 - Menno Simons Christian School

... Heat is produced or absorbed, starting material is used up, there is a change in colour, a material with new properties is formed, gas bubbles form in a liquid, a precipitate forms in a liquid and the change is difficult to reverse. 7) In the table below list whether there is a chemical or physical ...
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The origin and status of the Arrhenius equation
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Endothermic And Exothermic Reactions
Endothermic And Exothermic Reactions

... A chemical reaction that absorbs energy from its surroundings. More energy is required to break the bonds in the reactants than is released by the formation of bonds in the products. In these reactions, heat is shown as one This is a typical graph of an of the reactants endothermic reaction with the ...
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Transition state theory



Transition state theory (TST) explains the reaction rates of elementary chemical reactions. The theory assumes a special type of chemical equilibrium (quasi-equilibrium) between reactants and activated transition state complexes.TST is used primarily to understand qualitatively how chemical reactions take place. TST has been less successful in its original goal of calculating absolute reaction rate constants because the calculation of absolute reaction rates requires precise knowledge of potential energy surfaces, but it has been successful in calculating the standard enthalpy of activation (Δ‡Hɵ), the standard entropy of activation (Δ‡Sɵ), and the standard Gibbs energy of activation (Δ‡Gɵ) for a particular reaction if its rate constant has been experimentally determined. (The ‡ notation refers to the value of interest at the transition state.)This theory was developed simultaneously in 1935 by Henry Eyring, then at Princeton University, and by Meredith Gwynne Evans and Michael Polanyi of the University of Manchester. TST is also referred to as ""activated-complex theory,"" ""absolute-rate theory,"" and ""theory of absolute reaction rates.""Before the development of TST, the Arrhenius rate law was widely used to determine energies for the reaction barrier. The Arrhenius equation derives from empirical observations and ignores any mechanistic considerations, such as whether one or more reactive intermediates are involved in the conversion of a reactant to a product. Therefore, further development was necessary to understand the two parameters associated with this law, the pre-exponential factor (A) and the activation energy (Ea). TST, which led to the Eyring equation, successfully addresses these two issues; however, 46 years elapsed between the publication of the Arrhenius rate law, in 1889, and the Eyring equation derived from TST, in 1935. During that period, many scientists and researchers contributed significantly to the development of the theory.
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