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New AQA C3 revison guide
New AQA C3 revison guide

... New AQA UNIT 3 GCSE REVISION NOTES The Periodic Table History At the start of the 1800s quite a lot of elements had been discovered, but there had been no real attempt to organize them. Newlands, an English chemist and Mendeleev, a Russian chemist both worked on the problem by arranging the elements ...
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... reaction to proceed by igniting the bubbles or balloons. The more H2O that is formed during the reaction, the bigger the bang. Explain the following observations. a. A bubble containing just H2 makes a quiet “fffft” sound when ignited. b. When a bubble containing equal amounts of H2 and O2 is ignite ...
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FE Review Chemistry - UTSA College of Engineering
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< 1 ... 180 181 182 183 184 185 186 187 188 ... 281 >

Transition state theory



Transition state theory (TST) explains the reaction rates of elementary chemical reactions. The theory assumes a special type of chemical equilibrium (quasi-equilibrium) between reactants and activated transition state complexes.TST is used primarily to understand qualitatively how chemical reactions take place. TST has been less successful in its original goal of calculating absolute reaction rate constants because the calculation of absolute reaction rates requires precise knowledge of potential energy surfaces, but it has been successful in calculating the standard enthalpy of activation (Δ‡Hɵ), the standard entropy of activation (Δ‡Sɵ), and the standard Gibbs energy of activation (Δ‡Gɵ) for a particular reaction if its rate constant has been experimentally determined. (The ‡ notation refers to the value of interest at the transition state.)This theory was developed simultaneously in 1935 by Henry Eyring, then at Princeton University, and by Meredith Gwynne Evans and Michael Polanyi of the University of Manchester. TST is also referred to as ""activated-complex theory,"" ""absolute-rate theory,"" and ""theory of absolute reaction rates.""Before the development of TST, the Arrhenius rate law was widely used to determine energies for the reaction barrier. The Arrhenius equation derives from empirical observations and ignores any mechanistic considerations, such as whether one or more reactive intermediates are involved in the conversion of a reactant to a product. Therefore, further development was necessary to understand the two parameters associated with this law, the pre-exponential factor (A) and the activation energy (Ea). TST, which led to the Eyring equation, successfully addresses these two issues; however, 46 years elapsed between the publication of the Arrhenius rate law, in 1889, and the Eyring equation derived from TST, in 1935. During that period, many scientists and researchers contributed significantly to the development of the theory.
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