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Tenacity Challenge Quiz Bowl Subject Matter Concepts
Tenacity Challenge Quiz Bowl Subject Matter Concepts

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... A dissociation reaction is one that forms ions. If a molecule is made up on ions it might be able to be dissolved in water. Table salt (NaCl) is an example of a compound that is easily split into the Na+1 and the Cl-1 ions that make it up. Ions are charged particles that are very much similar to an ...
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... methods.5 The reaction path and potential energy surface were obtained by CASSCF and MRCI calculations with large, correlation consistent basis sets. The theoretical rate constant and activation energy are in excellent agreement with experiment. The rates for BCl + H, BCl + Cl, BH + H, BH + Cl, and ...
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South Pasadena · AP Chemistry

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... Too much energy is needed to remove 4 electrons from an atom. Too much energy is needed to insert 4 electrons into an atom in order to overcome the repulsive forces between like charges. 28. Why do elements of groups 6 and 7 form ions of charge –2 and –1 respectively? By gaining electrons they achie ...
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Transition state theory



Transition state theory (TST) explains the reaction rates of elementary chemical reactions. The theory assumes a special type of chemical equilibrium (quasi-equilibrium) between reactants and activated transition state complexes.TST is used primarily to understand qualitatively how chemical reactions take place. TST has been less successful in its original goal of calculating absolute reaction rate constants because the calculation of absolute reaction rates requires precise knowledge of potential energy surfaces, but it has been successful in calculating the standard enthalpy of activation (Δ‡Hɵ), the standard entropy of activation (Δ‡Sɵ), and the standard Gibbs energy of activation (Δ‡Gɵ) for a particular reaction if its rate constant has been experimentally determined. (The ‡ notation refers to the value of interest at the transition state.)This theory was developed simultaneously in 1935 by Henry Eyring, then at Princeton University, and by Meredith Gwynne Evans and Michael Polanyi of the University of Manchester. TST is also referred to as ""activated-complex theory,"" ""absolute-rate theory,"" and ""theory of absolute reaction rates.""Before the development of TST, the Arrhenius rate law was widely used to determine energies for the reaction barrier. The Arrhenius equation derives from empirical observations and ignores any mechanistic considerations, such as whether one or more reactive intermediates are involved in the conversion of a reactant to a product. Therefore, further development was necessary to understand the two parameters associated with this law, the pre-exponential factor (A) and the activation energy (Ea). TST, which led to the Eyring equation, successfully addresses these two issues; however, 46 years elapsed between the publication of the Arrhenius rate law, in 1889, and the Eyring equation derived from TST, in 1935. During that period, many scientists and researchers contributed significantly to the development of the theory.
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