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Water Cycle  Precipitation -> Runoff -> Evaporation-> Transpiration-> Condensation  Sun powers evaporation, precipitation, and transpiration  Reservoirs – Surface water (oceans, rivers, lakes), Glaciers, Groundwater (Aquifers), Water Vapor Atmospheric Gas, Living Organisms Importance  Water is essential to living organisms for a variety of reactions and cell processes  Water’s high heat storage distribute heat and determine regional and local climates  Water is a greenhouse gas – essential for maintaining Earth’s temperature – BUT too much greenhouse gas can be a bad thing  Sculpts landscapes  It is the universal solvent, often interacts with the movement of other cycles because it transports them  The water cycle is nature’s natural water purifier (evaporation and underground bacteria)  Water is a necessity in industry, waste management How humans alter  Overuse – use faster than it can replenish  Increase pollutants in runoff  Reduce infiltration – hard paved surfaces prevent recharging of groundwater  Accelerate topsoil erosion  Increase risk of flooding – when we drain and fill wetlands for farming or urban development  Alter weather – deforestation reduces transpiration of rainforests, the primary source of rainfall in rainforests. Reduced shade also evaporates water before it can permeate the soil. Carbon Cycle  Found in the atmosphere as a gas (CO2), dissolvable in water,  Producers pull carbon from the atmosphere or water for the process of photosynthesis  Consumers take in carbon by ingesting producers or other consumers  Producers and consumers release carbon as a product of respiration  Carbon can be incorporated into marine and terrestrial sediments and can be compressed into fossil fuels  Reservoirs – the ocean is the largest reservoir, calcium carbonate found in shells, marine sediments (decomposers release insoluble carbonates from dead marine organisms) forming limestone as well, fossil fuels (oil, natural gas, coal), tropical rain forests, tundra (permanently frozen plant matter), atmosphere, living organisms Importance  Carbon is the basic building block of the four major macromolecules (carbohydrates, lipids, proteins, & nucleic acids) as well as other important organic molecules  Carbon dioxide is a greenhouse gas – essential for maintaining Earth’s temperature – BUT too much greenhouse gas can be a bad thing How humans alter  The extraction and burning of huge quantities of fossil fuels that have taken millions of years to form have released large amounts of carbon dioxide to the atmosphere  The clear-cutting of carbon-absorbing vegetation (especially tropical rain forests) have released large amounts of carbon to the atmosphere  The increased concentration of carbon dioxide and other greenhouse gases (methane, water) are warming our planet and projected to change Earth’s climate this century Nitrogen Cycle  N2 cannot readily be absorbed and used by plants and animals, so we rely on electrical discharges (lightening) and nitrogen fixing bacteria to make it usable for plants  Animals consume plants or other consumers to obtain their nitrogen  Reservoirs – the atmosphere (78%) Remember “FNAAD, ANPAN” Fixation-------------- Ammonia Nitrification---------- Nitrates, Nitrites Assimilation---------- Proteins (Bacteria and cyanobacteria combine gaseous N2 with hydrogen to make ammonia NH3 and/or ammonia ions NH4+ which they use as a nutrient for themselves. They excrete the rest of the ammonia into the soil or water) (Ammonia not taken up by plants is converted by soil bacteria into nitrate ions NO3- which are easily taken up by the roots of plants) (Plants use the ammonia or nitrate ions to produce proteins, nucleic acids, and vitamins. Consumers will ingest plants or other consumers and do the same) ----Organism Death/Decomposition----------------------------------------------------------------------------------------------------------------------------------------Ammonification------ Ammonia (Decomposer bacteria convert detritus material into ammonia NH3 and ammonia ions NH4+) Denitrification-------- Nitrogen Gas (Specialized bacteria in waterlogged soil and the bottoms of lakes, oceans, swamps, and bogs covert ammonia NH3 and ammonia ions NH4+ back into nitrate ions and then into nitrogen gas and nitrous oxide gas. These are released back to the atmosphere to begin the cycle again.) Importance  Nitrogen is a key component in macromolecules such as proteins, vitamins, and nucleic acids (DNA and RNA)  Nitrogen is a limiting factor for primary productivity Human Impacts  We add nitric oxide NO to the atmosphere as we burn fuel at high temperatures (cars, jets). This gas is converted into nitrogen dioxide gas NO2 and nitric acid vapor HNO3 which falls to the earth as acid deposition aka acid rain.  Anaerobic bacteria break down inorganic fertilizer or organic manure and contribute nitrous oxide N2O to the atmosphere. Nitrous oxide is a greenhouse gas.  Deforestation releases large quantities of nitrogen stored in soils and plants, back to a gas  Agricultural runoff of fertilizers, animal manure, and sewage discharge add excess nitrates NO3- to bodies of water. This can lead to eutrophication (algal blooms, which bring in more bacteria as algal decomposes, decreasing the oxygen in aquatic environment, often resulting in fish kills)  Harvesting of crops, irrigation, and burning or clearing of grasslands and forests can cause nitrogen to wash away from the topsoil.  We have more than doubled the annual release of nitrogen from the land due to the inorganic fertilizers Phosphorus Cycle  Very slow to cycle in comparison to water, carbon, and nitrogen  Water erodes away inorganic compounds, that include phosphates, from rocks  Water carries dissolved phosphates into the soil where they can be absorbed by producers  Consumers take in phosphates by ingesting producers  Phosphates can be lost from the cycle for long periods when it is washed to the ocean and held in the marine sediment for millions of years  Reservoirs – Phosphate salts containing phosphate ions, terrestrial rock formations, and ocean bottom sediments. Does not include the atmosphere Importance  Phosphate ions PO43- are an important nutrient  Phosphate is incorporated into nucleic acids, ADP, and ATP, bones, and teeth Human Impacts  Humans mine phosphate salts which are added to fertilizers and applied to agricultural fields. Excess phosphates from runoff can also cause eutrophicaton (algal blooms, which bring in more bacteria as algal decomposes, decreasing the oxygen in aquatic environment, often resulting in fish kills)  Clearing of rain forests causes phosphates to wash away Sulfur Cycle  Volcanoes release sulfur dioxide (a colorless, poisonous gas with a rotten egg smell). Decomposers in flooded swamps, bogs, and tidal flats also release sulfur dioxide.  Sulfate salt particles enter the atmosphere from sea spray, dust storms, and forest fires.  Plants absorb sulfate ions, and incorporate them into proteins.  Marine algae produce large amounts of volatile dimethyl sulfide (DMS – CH3SCH3). DMS is the nuclei/particle around which water droplets condensate (aka cloud seeds)  In areas like wetlands and tidal flats, bacteria convert sulfate ions to sulfide ions. These react with metal ions which form metal ores.  Reservoirs – underground rocks and minerals in the form of sulfate salts S042Importance  Essential nutrient – Used in amino acids, proteins, enzymes, keratin Human Impacts  Changes in DMS emissions can affect cloud cover and climate (DMS is a byproduct of paper manufacturing)  DMS can be converted to sulfur dioxide, then to sulfur trioxide gas, and to sulfuric acid. It can also react with ammonia to produce sulfate salts. These can fall to the earth in the form of acid deposition/acid rain.  We refine sulfur containing oil to make gasoline and burn sulfur containing coal and oil, once in the atmosphere it contributes to acid rain.  We extract metals such as copper, lead, and zinc from sulfur containing compounds in rocks.