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Muller mixers  Different mixing action  Mulling is smearing or rubbing action similar to that in mortar and pestle  Wide, heavy wheels of the mixer did the same job  Pan is stationary & central vertical shaft is driven – causing the muller wheels to roll in circular path on solid  Rubbing action results from slip of the wheel on solids  Plows – guide solids under wheels or to discharge opening  Axis of the wheels is stationary & pan is rotated  Good mixer for batches of heavy solids and pastes  Effective in coating the granular particles with liquid 1 Muller Mixer Pug Mills  Mixing is done by blades or knives set in helical pattern on a horizontal shaft.  Open trough or closed cylinder  Cut, mixed and moved forward  closed mixing chamber - Single shaft  Open trough – double shaft for more rapid & thorough mixing  Mostly cylindrical in shape  Heating or cooling jackets  Blend and homogenize clays, mix liquids with solids to form thick heavy slurries 3 Pugmills Mixers for free flowing solids  Lighter machines are there for dry powders and thin pastes  Ribbon blender  Tumbling mixer  Vertical screws  Impact wheel / rotating disc 5 Ribbon Blenders  Horizontal trough – central shaft and a helical ribbon agitator  Two counteracting ribbon mounted on same shaft  One moving in one direction  Second in other direction  Ribbon – continuous or interrupted  Mixing – turbulence by counteracting agitators  Mode of operation – batch or continuous  Trough – open or closed  Moderate power consumption 6 Ribbon Blender Ribbon Blender Internal screw mixers  Vertical tank containing a helical conveyor that elevates and circulates the material  For free flowing grains and light solids  Double motion helix orbits about the central axis of the conical vessel visiting all parts of the vessel  Mixing is slower than ribbon blenders but power requirement is less 9 Internal Screw Mixer Internal Screw Mixer Tumbling mixer  Partly filled container rotating about horizontal axis  Mostly no grinding element  Effectively mix – suspension of dry solid in liquid, heavy dry powders  Wide size range and material of construction 1. Double cone mixer  Batch – charged from above – 50 to 60 %full  Free flowing dry powders  Close end of vessel – operated 5 to 20 min 2. Twin shell blender  Two cylinder joined to form a V  rotated about horizontal axis  More effective than double cone mixer 12 Double Cone Mixer Twin Shell Blender Impact wheels  Operating continuously by spreading them out in a thin layer under centrifugal action  Several dry ingredients are fed continuously near the high speed spinning disk 10 to 27 in. in diameter throwing it in a stationary casing.  Intense shear cause mixing  1750 to 3500 rpm  Several passes through same or in series  1 to 25 tons/hr  Fine light powders like insecticides 15 Impact Wheels Power Requirement for mixing  Mechanical Energy is required for mixing  Large for heavy plastics masses  Relatively small for dry solids  Only part of the energy supplied is directly useful and this part is small  Mixers  Work intensively on small quantities  Work slowly on large quantities  Light machines waste less energy than heavier one  The shorter the mixing time required to bring the material to homogeneity, larger the useful fraction of energy supplied  Major portion of energy supplied appears as heat 17 Criteria of Mixing Effectiveness: Mixing Index  Performance criteria o Time required for mixing o Power load of mixer o Properties of product from mixer  Effective mixing objectives o Rapid mixing action with less time o Minimum power required o High degree of uniformity (homogeneous product) 18 Mixing index for cohesive solids/pastes  The degree of uniformity by sample analysis is a measure of mixing effectiveness  Sampling – number of spot samples  A – tracer  B – tracer free  μ – overall concentration of tracer in mixture  N – number of spot samples  xi – conc. of tracer in ith sample  x’ – average concentration of tracer in all spot samples 19  If N is very large, i.e; N infinite  average conc. will be equal to overall conc. of tracer (x’ = µ)  If N is very small, i.e; N zero  average conc. and overall conc. of tracer will be appreciably different ((x’ ≠ µ)  If the mixture is perfectly mixed  conc. of each sample is same as average conc. (xi = x’)  If the mixture is not completely mixed  conc. of each sample is different from average conc. (xi ≠ x’) 20 Statistical method/procedure to find out quality of mixing  Assumption – methods used for determining the conc. of tracer are highly accurate  Standard deviation of xi about the average value of x’ is a measure of quality of mixing i.e. xi – x’  Mean deviation of conc.  Mean square value of deviation  Root mean square value – standard deviation  Population standard deviation - σ  Sample standard deviation – s  Bessel’s correction 21 So the sample standard deviation  low value of s  Good mixing  High value of s  Poor mixing  More general measure of mixer effectiveness is given by ‘Mixing Index’ 22 Mixing index is the ratio of standard deviation at zero time to the standard deviation at any time  At t = 0, there will be two layers in the mixer; one containing tracer material and the other containing tracer free material.  Standard deviation at zero time is given by: 23  Mixing index for pastes  Ratio of max standard deviation to the instantaneous standard deviation  Ip is unity at the start and increases as mixing  Theoretically Ip would become infinity at long mixing times but actually it does not occur. 24 Mixing index for granular / non cohesive solids  As for granular solids  Intense agitation is not required  Less power load  Relatively less heat load  Mixing index for granular solids based  Not on zero mixing condition  But on standard deviation that would be observed with completely random, fully blended mixture  At t = 0, there is some mixing for these type of solids  For granular solids – conc. is expressed as number fraction of tracer particles 25 Mixing index for granular solids  Sampling – number of spot samples  A – tracer  B – tracer free  μp – overall concentration of tracer in mix  N – number of spot samples  n – average no. of particles per sample  xi – conc. of tracer in ith sample  x’ – average no. fraction of tracer in each sample 26 Statistical method/procedure to find out quality of mixing  Standard deviation is measure of quality of mixing  Mean deviation of conc.  Mean square value of deviation  Root mean square value – standard deviation  Sample standard deviation - s  Population standard deviation – σ  Bessel’s correction factor 27  Standard deviation for completely random mix  For granular solids mixing index is defined as 28 Mixing Index at zero time for granular solids  Standard deviation at complete mixing – granular solid  Standard deviation at zero mixing - paste  For n = 1 , two relations are identical  For a sample of one particle, taken from a mixture of granular solids, the analysis shows either xi = 0 or xi = 1 i.e. the same as with completely unmixed material at zero time, So, S.D. at zero mixing can be used for granular solids when n = 1  So, mixing index at zero time for granular solids is; 29 Rate of Mixing  Rate is proportional to driving force  Time calculated for given degree of mixing 30 Axial Mixing  Mixing  Radial  Axial  Degree of axial mixing is measured by injecting the small amount of tracer into feed and check the conc. of tracer at outlet  Max conc. Of tracer  Length of time 31 Quiz no. 1 th course: chapter no. 28 from 5 edition date: 6th December, 2012 time: 12:00 pm venue: seminar hall marks: 10 fill in the blanks, mcq’s, true/false, short questions no. Of minutes = no. Of 32