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The Chemistry of Life Chapter 2 vocabulary  Atom the most basic and smallest unit of matter – Nucleus  center of the atom  holds protons and neutrons – Contains subatomic particles  called protons, electrons and neutrons  Discuss next diagram Atoms  Nucleus;  Protons; + charge; mass = 1AMU  Neutrons; no charge; mass = 1AMU Electrons: - charge; no mass  vocabulary   Element specific atoms of one type form pure substances Over 100 elements/pure substances exist Ca calcium  H hydrogen  O oxygen  Na sodium  C carbon  Periodic table    Elements are organized in a table and assigned a number Number atomic number Table periodic table This your new friend…at least for this next unit!  Get use to it  Atomic Number     Defines the element Is equal to the number of protons Is equal to the number of electrons in a neutral atom Always the whole number An Element in the Periodic Table Section 2-1 Atomic Number 6 C Carbon 12.011 Atomic Mass Go to Section: Atomic Mass    Is equal to the number of protons and neutrons in the nucleus of the atom May not be a whole number on the periodic table In biology you may round up the mass number to a whole number To find the number of Neutrons  Atomic mass – atomic number = Neutrons Isotopes of Carbon Nonradioactive carbon-12 Nonradioactive carbon-13 6 electrons 6 protons 6 neutrons 6 electrons 6 protons 7 neutrons Radioactive carbon-14 6 electrons 6 protons 8 neutrons Isotopes have the same number of protons and electrons but have a different number of neutrons Time to play… Candium isotope lab!!! Energy Levels 1st 2e- 2nd 8e- 3rd 8e4th18e- Valence Electrons   Outer level Electrons Bonding Electrons How are things kept together  Ionic Bonds      Covalent bonds     Can create slightly different charges Strongest chemical bond Orbitals/shells overlap and electrons bounce back and forth Van der Waals forces   Transferring of electrons Create ions Opposite charged particles are attracted to each other Electrons are gained/lost Happens when molecules are super close together Hydrogen bonding-weak bonds Drawing molecules showing Ionic Bonding     Draw all atoms showing protons, and electrons in their energy levels Decide which electrons must be transferred in order to fill all of the atoms outer level Draw the electrons being transferred Show the resulting charge on the Ions Ionic Bonding Sodium atom (Na) Chlorine atom (Cl) Sodium ion (Na+) Chloride ion (Cl-) Transfer of electron Protons +11 Electrons -11 Charge 0 Protons +17 Electrons -17 Charge 0 Protons +11 Electrons -10 Charge +1 Protons +17 Electrons -18 Charge -1 Ionic Bonding Section 2-1 Sodium atom (Na) Chlorine atom (Cl) Sodium ion (Na+) Chloride ion (Cl-) Transfer of electron Protons +11 Electrons -11 Charge 0 Protons +17 Electrons -17 Charge 0 Protons +11 Electrons -10 Charge +1 Protons +17 Electrons -18 Charge -1 Draw the following molecules showing them form ionic bonds   KF MgCl2 Chemical formulas     CO2 3 Atoms H2O 3 Atoms Ca(OH)2 5 Atoms 2C6H12O6 48 atoms Covalent Bonding    Sharing of electrons No ions are formed Sharing of electrons holds it together. Guided/independent practice  Chemistry worksheet…time to think! Water     Most abundant compound found in living things. Water is a molecule (H2O) Water is a polar molecule. (unequal sharing of electrons) Hand out chemistry worksheet! Water  Facts     It is a neutral molecule Water is the single most abundant compound on earth It expands when it freezes It floats when frozen     What advantage does this play in the survival of fish and plants 75% of earth is water The human body is 70% water Ph of 7.0 Properties of Water  Its Polar It has a negative end and a positive end  Uneven sharing of electrons   High heat capacity  Absorb  Hydrogen bonds Because of the uneven charge water atoms can attract each other  Cohesion: attraction between molecules of the same substance    Insects walking on water Adhesion: attraction between molecules of different substances  Water drawn up a plant (capillary action) Hydrogen Bonding Water demo  Water lab Acids, Bases, and the pH scale  Water is the universal solvent       Most compounds will dissolve in water Remember 75% of most animals are water H20 → H+ + OHWater → Hydrogen ion + Hydroxide ion Only about one water molecule in 55 million will form a hydrogen ion H+ = OH- , so water is always neutral  PH scale – measures the concentration of H+ and OH- ions.  Ranges from 0-14 At 7 the concentration of H+ and OH- is equal. (pure water) Acid – H+ ions, 0-6 Alkaline or base- OH- ions, 8-14 Each step represents a factor of 10     pH Scale Increasingly Basic Oven cleaner Increasingly Acidic Neutral Go to Section: Bleach Ammonia solution Soap Sea water Human blood Pure water Milk Normal rainfall Acid rain Tomato juice Lemon juice Stomach acid Acids Any compound that gives off a hydrogen ion (H+) in a solution. – HCl – Stomach acid – Lemon juice – Tomato juice Bases Any compound that will produce hydroxide ions (OH-) in a solution. – Human blood – Sea water – Oven cleaner – Bleach – soap Time to play… Ph lab Buffers Facts – Most cells in animals must generally be kept at a pH level between 6.5 and 7.5 • Human blood has a pH of 7.4 – If the body’s pH level goes to high or too low then cells do not work – Maintaining pH levels is important for homeostasis – Large changes in pH are controlled by substances called buffers Examples of buffer in the body’s cells – Carbonic Acid (H2CO3) – (H2CO3) → HCO3- + H+ – Carbonic acid dissociates in water to form bicarbonate ion and H ions Chemical Reactions Everything that happens in an organism is based on chemical reactions Definition: a chemical reaction is a process that changes one set of chemicals into another set of chemicals – Cellular respiration – Formation of Carbonic Acid from carbon dioxide and water Mixture  2 or more elements or compounds that are physically mixed together but not chemically combined.  Salt & pepper Earth’s atmosphere Salad soil    Solutions Evenly distributed throughout. Solvent; does the dissolving Solute; gets dissolved Water is the greatest solvent. NaCI Solution ClCl- Na+ Na+ Water Water NaCI Solution ClCl- Na+ Na+ Water Water Suspension  Unevenly distributed throughout. (settle out) Water & gas  Water & oil  Blood  4 Organic Compounds Carbon Compounds include Carbohydrates Lipids Nucleic acids Proteins that consist of that consist of that consist of that consist of Sugars and starches Fats and oils Nucleotides Amino Acids which contain which contain Carbon, hydrogen, oxygen Carbon, hydrogen, oxygen which contain which contain Carbon,hydrogen, oxygen, nitrogen, phosphorus Carbon, hydrogen,oxygen, nitrogen, Organic Compounds Organic compounds contains Carbon, Hydrogen and Oxygen Carbohydrates Main source of energy Monosaccharide (simple sugar)   Glucose – produced by green plants. Fructose – fruits, vegetables, honey. Disaccharides (double sugar)   Lactose – mammals milk. Sucrose – table sugar. Polysaccharides (complex sugar)    Cellulose (plants) Starch (plants) Glycogen (animals) Plants store carbohydrates as Starch Glucose Go to Section: Animals store carbohydrates as Glycogen in the liver and muscles Lipids Stored energy Fatty acids Saturated fatty acids – meat & dairy. Unsaturated fatty acids – plants. Phospholipids Waxes Oils Steroids Lipids What is it?   Fat, oils, and waxes Lipid cells together are know as adipose tissue, hey look at that spare tire! Adipose tissue acts to cushion vital organs Once your body creates a fat cell, it is yours for life, you can never get rid of it! Functions   Stores a huge amount of energy, even more than that carbohydrates But it is used for emergency situations when you run out of carbohydrates Types of lipids found in animals HDL     Known as the “good” lipid Found in vegetables, oils, and some nuts Helps clear out LDL of you system Exercise will increase the levels of HDL in an animals system LDL Triglycerides Proteins Made up of Amino acids 20 different amino acids Structural- cell, muscle, skin, organs. Movement Enzymes Proteins Examples of proteins  Muscle, insulin, hair Facts      Accounts for %50 of cells weight Used for support, storage, transport defense, signaling other cells Humans have 10s of thousands of different proteins Are made of monomers called amino acids There are 20 different amino acids What makes a protein function  The order of the amino acids Each protein has a specific order  The shape of a protein determines its function Homeostasis: too much acid-proteins unfold. To high a temperature: proteins unfold, to cold: proteins cant function 3-D Protein Nucleic Acids Deoxyribonucleic Acid (DNA) Ribonucleic Acid (RNA) Contains genetic information Controls the production of proteins Nucleotides    Phosphate Sugar base Enzymes Some reactions that are needed in life are too slow to happen by themselves. To speed up these reactions cell in plants and animals produce catalysts.   A substance that speeds up chemical reactions They work by lowering the activation energy Enzymes are proteins that act as biological catalysts    Always end in ase Lactase, carbonic anhydrase Very specific Catalyst Substance that reduces the amount of energy for a reaction to occur. Catalyst in cells are proteins called Enzymes. The substance that the enzyme works on are called a substrate. Enzymes are very selective. Enzyme animation http://www.nd.edu/~aostafin/CRCD/DOSS/ enzymeanimation3.gif Effect of Enzymes Section 2-4 Reaction pathway without enzyme Activation energy without enzyme Reactants Reaction pathway with enzyme Activation energy with enzyme Products Go to Section: Time to play… Enzyme lab Organic compounds lab