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					WARM-UP  Atomic   #11 JAN. 25 Theory States that matter is composed of discrete units called atoms The word "atom" comes from the ancient Greek adjective atomos meaning 'indivisible’ Essential Question: When and where do you think mankind originally began to ponder as to what makes up the elements and atoms? SUBATOMIC PARTICLES Name Symbol Charge Relative mass 1/1840 Actual mass Electron e- -1 Proton p+ +1 1 1.67 x 10-24 Neutron n0 0 1 1.67 x 10-24 crap 9.11 x 10-28 SYMBOLS  The symbol of an element contains the mass number and the atomic number: Mass Number Atomic Number SYMBOLS Find the: 1. Number of Protons 2. Number of Neutrons 3. Number of Electrons 4. Atomic Number 5. Mass Number Rh 104 45 Rhodium - 104 HISTORY OF THE ATOM The original idea of the atom came from Ancient Greece (400 B.C.)  Democritus – Greek Philosopher  He and his mentor Leucippus first described that all things were made up of “atoms”  WHO’S NEXT? Late 1700’s – John Dalton – England  Teacher – summarized results of his experiments and those of others in his Atomic Theory.  His idea combined ideas of elements with atoms  DALTON’S ATOMIC THEORY All matter is made up of tiny individual particles called atoms  Atoms of the same element are identical, those of different elements are different  Atoms of different elements combine in whole number ratios to form compounds  Chemical reactions involve the rearrangement of atoms. No new atoms are created or destroyed.  JJ THOMSON J.J. Thomson – English physicist, 1897  Made a piece of equipment that explored the properties of cathode rays.  Basically discovered that atoms of divisible  THOMSON’S MODEL Found the electron  Couldn’t find positive (for a while)  Said the atom was like plum pudding  A bunch of positive stuff, with the electrons able to be removed  PROTONS  Proton – positively charged pieces 1840 times heavier than the electron.  Eugene Goldstein used a modified cathode ray  Rutherford predicted its presence in the atom with gold foil experiment RUTHERFORD’S EXPERIMENT Ernest Rutherford was an English Physicist (1910)  Believed in the plum pudding model of the atom.  Wanted to see how big they are  Used radioactivity  Alpha particles – positively charged pieces given off by uranium  Shot them at gold foil which can be made a few atoms thick  HE EXPECTED The alpha particles to pass through without changing direction very much.  Because… The positive charges were spread out evenly. Alone they were not enough to stop the alpha particles  WHAT HE GOT HOW HE EXPLAINED IT Atom is mostly empty  Small dense, positive  Piece at center  Alpha particle are deflected by it if they get close enough  DENSITY OF THE ATOM Since most of the particles went through, it was mostly empty  Because the pieces turned so much, the positive pieces were heavy  Small volume, big mass, big density.  This small dense positive area is the nucleus  BOHR’S MODEL – 1915 Why don’t the electrons fall into the nucleus?  Move like planets around the sun.  In circular orbits at different levels  Amounts of energy separate one level from another  BOHR’S MODEL The further an electron is from the nucleus the more energy it has  There is no “in between” energy  It is like a ladder  BOHR’S IS NOT RIGHT EITHER! Bohr got closer than we had been so far, but it was still not right.  He gave us the idea of energy levels for electrons.  BUT his idea only worked for one atom  NEUTRONS No charge  Same mass as the proton  Discovered by James Chadwick during radioactivity experiments in 1932  QUANTUM MECHANICAL MODEL 1925 - Erwin Schrondinger used the results of the experiments done with the hydrogen atom to come up with the quantum mechanical model  This comes from a mathematical solution to the Schrodinger equation  The quantum mechanical model determines the allowed energies an electron can have and how likely it is to find the electron in various locations.  QMM Has energy levels for electrons  Orbits are not circular  It can only tell us the probability of finding an electron a certain distance from the nucleus.  MODERN VIEW The atom is mostly empty space  Two regions  Nucleus – protons and neutrons  Electron cloud – region where you might find an electron  ATOMIC THEORY TIMELINE ASSIGNMENT You are to create a timeline that maps out each significant event throughout history that involves the atomic theory.  There will be at least 8 events (all were covered in the notes)  For each event I want the:  Date  Person  What they contributed (IN COMPLETE SENTENCES).  A drawing or something of what they discovered. They need to be colored.  TICKET OUT THE DOOR 1. 2. 3. 4. What does the atomic number tell you about an element? What are the three subatomic particles, their relative masses, relative charges, and location(which region of the atom)? What is a compound? What is an isotope? WARM-UP #12 JAN. 26 An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons  Cations  When an element becomes positively charged it forms a cation  Anion  When an element becomes negatively charged it forms an anion What do you have to lose in order to become positively charged? THE PERIODIC TABLE The periodic table is based on the Modern Periodic Law  Came from the QMM  Set up in rows called periods    Indicate the main energy level Columns called groups or families  Similar properties  Dmitri Mendeleev was one of the first scientists to realize there was a trend in the properties of the elements CLASSIFYING We separate the periodic table several ways to help classify the elements  This includes dividing it by families, and type of element  Representative – group A  Transitions – group B  We split the table into these 2 major groups  Most of what we deal with deal with is in group A or the representative elements  METAL ~ NONMETAL ~ METALLOID These are three of our other main classifications  Elements that fit into these groups have specific properties  METALS  Most metals are solid at room temperature Which one is the exception?  Mercury – Hg   Generally good conductors of heat and electric current  Sea of free floating electrons Usually form cations  Usually malleable and ductile  NONMETAL Less similarities in the nonmetals  Typically poor conductors of heat and electric current  Solid nonmetals tend to be brittle   Carbon, Sulphur METALLOID These elements have properties that are similar to both metals and nonmetals  Semiconductors    Can be used to produce superconductors Boron, silicon, arsenic PERIODIC TABLE ASSIGNMENT Pick 3 elements, one from each subgroup (metal, nonmetal, metalloid)  Research each element:  Draw the symbol as you would see it on the periodic table  Label the atomic number and mass number  Tell me where the element is found and how we use it   Products, industry, etc. Describe some of its properties  Draw a picture of what it looks like naturally  These should be colored  WARM-UP   #13 JAN. 27 Valence Electrons - are the electrons of an atom that can participate in the formation of chemical bonds with other atoms. Electron dot diagrams - diagrams that show the bonding between atoms of a molecule and the lone pairs of electrons that may exist in the molecule HOW DO ELEMENTS FORM IONS AND WHY?  All elements are trying to get the same number of electrons as the nearest noble gas   Far column on the right This is where valence electrons come in VALENCE ELECTRONS All atoms have valence electrons  These are the electrons responsible for forming bonds  They are the furthest from the nucleus  They fill the outermost energy level  These determine the properties of the atom, such as stability.   Every element can only have 8 valence electrons  They WANT to have 8 like the noble gases  Helium only has 2 electrons TOTAL, so some elements are content VALENCE ELECTRONS  You can determine how many valence electrons for Group A by looking at the groups number VALENCE ELECTRONS   We represent valence electrons using electron dot diagrams. Electron dot diagrams show the element symbol with dots representing the valence electrons BOHR’S MODEL  Shows  1st ALL of the element’s electrons – 2e 2nd – 8e 3rd – 18e 4th – 32e- NITROGEN N ALUMINUM Al IONS Atoms form ions based on the number of valence electrons Group VIII A 8 valence electrons (8 ve-) What 0 is the charge as an ion?  Positive ions are called cations These are formed when an atom loses electrons  The metals usually form cations   Negative ions are called anions These are formed when an atom gains electrons  The nonmetals usually form anions  When an atoms forms an ion it changes size because it becomes stable  Cations are much smaller the atom in which they form  Anions are much bigger than the atom from which they form TICKET OUT THE DOOR 1. 2. 3. 4. What does the atomic number tell you about an element? What are the three subatomic particles, their relative masses, relative charges, and location(which region of the atom)? What is a compound? What is an isotope? PRACTICE  Draw e- dot diagram, bohr model diagram, and tell what charge each will have as an ion        Sodium Sulfur Silicon Oxygen Argon Chlorine Beryllium WARM-UP Draw #14 JAN. 30 e- dot diagram, bohr model diagram, and tell what charge each will have as an ion:  Fluorine  Neon  Carbon REVIEW  What are your three subgroups of elements on the periodic table? Metals  Non-metals  Metalloids   What  is an isotope? Atoms that have the same number of protons but different number of neutrons. REVIEW  What the atomic number equal to?   What is the mass number equal to?   Number of protons Number of protons and neutrons What is a valence electron?  Electron found on the out shell of an atom. There can only be 8 total. TYPES OF CHEMICAL BONDS  Ionic Bonds Form between positive and negative ions  Ex: salt forms when sodium reacts with chlorine   Covalent Bonds Form when atoms share electrons  Ex: Silicon dioxide forms when one silicon atom and two oxygen atoms share electrons in that outermost energy level   Metallic Bonds  Form when electrons are shared by metal ions MINERALS A mineral is a naturally occurring, inorganic solid with an orderly crystalline structure and definite chemical composition.  There are nearly 4000 known minerals  NATURALLY OCCURRING A mineral forms by natural geologic processes.  Synthetic gems are not minerals SOLID SUBSTANCE Minerals are solids within the temperature ranges that are normal for Earth’s surface  Definite shape  Definite volume  ORDERLY CRYSTALLINE STRUCTURE  Their atoms or ions are arranged in an orderly and repetitive manner DEFINITE CHEMICAL COMPOSITION Every mineral is made up of a specific compound. Each sample of that mineral is made of the same compound.  Different minerals are different compounds  Ex: Quartz – Si02  GENERALLY CONSIDERED INORGANIC  What do you think it means to be organic?  Organic means that it is a compound containing carbon  Most minerals do not contain carbon  We say generally because there are some animals that secrete compounds considered minerals  Ex: Calcite : calium carbonite SOURCE http://www.rocksandminerals .com/uses.htm TICKET OUR THE DOOR 1. 2. 3. 4. What is a mineral? Give me two characteristics a mineral must have. Give an example of a mineral and one of its uses. Draw an e- dot diagram and Bohr model for Phosphorus 1. LOCATED IN GROUP 5A WARM-UP  What are five characteristics of a mineral? #15 JAN. 31  Coal forms from ancient plant matter that has been compressed over time. Do you think coal is a mineral? HOW MINERALS FORM  There are four major processes by which minerals form:  Crystallization from magma  Precipitation  Changes in pressure and temperature  Formation from hydrothermal solutions CRYSTALLIZATION FROM MAGMA Magma is molten rock  As magma cools, elements combine to form minerals  First minerals are usually rich in iron, calcium, and magnesium.  As minerals continue to form the magma changes composition forming minerals rich in sodium, potassium, and aluminum  PRECIPITATION Water contains dissolved substances  As the water evaporates some of the dissolved substances can react to form minerals.  Limestone and Halite are common examples of precipitation  PRESSURE AND TEMPERATURE Some minerals form when existing minerals are subjected to changes in pressure and temperature  An increase in pressure can cause a mineral to recrystallize while still solid  Atoms are rearranged  Temperature change can cause minerals to become unstable and form new minerals that are stable at the new temperature.  HYDROTHERMAL SOLUTIONS 100° C – 300° C  Very hot mixture of water and dissolved substances  When they come into contact with existing minerals, chemical reactions take place and form new minerals  Minerals can also form when these solutions cool  MINERAL GROUPS  There are 6 groups of minerals that we will discuss       Silicates Carbonates Oxides Sulfates/Sulfides Halides Native Elements SILICATES Most common  Contain silicon-oxygen tetrahedron  Groups based upon tetrahedron arrangement        Olivine Pyroxene Amphibole Micas Feldspars Quartz OLIVINE  Independent tetrahedron PYROXENE GROUP  Tetrahedrons are arranged in chains AMPHIBOLE GROUP  Tetrahedron are arranged in double chains MICAS Tetrahedron are arranged in sheets  Two types  Biotite – dark  Muscovite - light  FELDSPARS Three-dimensional network of tetrahedron  Two types:  Orthoclase  Plagioclase  QUARTZ  Three dimensional network of tetrahedron CARBONATES A major rock-forming group  Found in the rocks limestone and marble  Calcite and Dolomite are carbonate minerals  OXIDES Minerals that contain oxygen and one or more other elements.  Rutile – TiO2 form as magma cool  Corundum – Al2O3 forms when existing minerals are subjected to changes in temperature and pressure  SULFATES AND SULFIDES  Minerals that contain sulfur Anhydrite – CaSO4  Gypsum  Pyrite – fools gold  HALIDES Minerals that contain a halogen  Salts  Halite – table salt  Fluorite  NATIVE ELEMENTS  Group of minerals that exist in relatively pure form       Gold Silver Copper Sulfur Diamond Graphite WARM-UP #16 FEB. 1  Think of and list as many properties as you can that help us identity minerals. Again, these are different than the characteristics of minerals.  Why is it important to identify minerals? MINERAL PROPERTIES   Minerals are classified by a set of specific properties These are considered intensive properties  This means they don’t depend on the amount of the substance, but the composition instead COLOR Color is the first thing you will notice about a mineral  Do you think this is a good indicator of what a mineral is made of?  Not always  A very small difference in amount of elements present can change the color of the mineral  LUSTER Luster describes how light is reflected off the surface of a mineral  Minerals that have the appearance of metals are said to be metallic.  Nonmetallic luster is described in many different ways:  Vitreous  Glassy  Pearly  Silky  Earthy  Adamantine  Sub-metallic  STREAK Streak is the color of a mineral in its powdered form.  You can obtain this by rubbing a mineral across a streak plate (unglazed porcelain)  Streak does not usually vary even if the color does  CRYSTAL FORM  Visible expression of the internal arrangement of atoms HARDNESS A measure of the resistance of a mineral to being scratched  One of the most useful properties in identifying minerals  We use the Mohs scale of hardness CLEAVAGE AND FRACTURE Cleavage and fracture both deal with how a mineral breaks apart Cleavage is the tendency to break along a flat even surfaces Fracture is the uneven breakage of minerals  Mica shows cleavage; breaking in even flat sheets FRACTURE DENSITY Density is a property of all matter that is the ratio of an object’s mass to its volume.  Think of it as how compact the substance is  Grams Cubic centimeters or milliliters PRACTICE A 6.75 g solid with a volume of 5.35 cm3. Find the density. D = 6.75g / 5.35 cm3  D = 1.26 g/cm3 OTHER PROPERTIES  Some minerals have distinctive feels  Talc is soapy, and graphite feels greasy  Some minerals are magnetic like magnetite  Some have distinctive smells like sulfur  Calcite reacts chemically with hydrochloric acid and will fizz REFLECTION In your journals, tell me what you did today and how it is important.  Describe the different properties of minerals and how you used them today to determine the identity of various minerals.  What were some properties of specific minerals that gave their identity away relatively easily.  WARM-UP   #17 FEB. 2 What are the differences between ionic bonds, covalent bonds, and metallic bonds? (use your notes) What are halogens? TICKET OUT THE DOOR Name 4 properties of minerals used for identification.  How do we calculate density?  What is the difference between cleavage and fracture? 
 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
									 
                                             
                                             
                                             
                                             
                                             
                                             
                                             
                                             
                                             
                                             
                                            