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Where it Starts--Photosynthesis  Obtain   energy Autotrophs Heterotrophs  Metabolism—biochemical energy   Photosynthesis Cellular Respiration processes release  Food   energy stored in chemical bonds Exergonic (cellular respiration) Endergonic (photosynthesis)  Energy transfers from endergonic to exergonic through ATP  Chlorophyll    Plants Algae Some bacteria  Transfer sun’s energy into chemical bonds  Three    stages Light-capturing Light-dependent Light-independent  CO2 + H2O => C6H12O6 (glucose) + O2  Wavelength  Spectrum  Photons   Packets of particle-like light Fixed energy  Energy  Low energy = long wavelength   level Microwaves, radio waves High energy = short wavelength  Gamma rays, x-rays  The light that you see is REFLECTED, not absorbed.  Therefore, a green plant is reflecting the green part of the spectrum (and photons of that energy), not absorbing them.  Molecules that absorb photons of only a particular wavelength  Chlorophyll a    Absorbs red, blue, violet light Reflects green, yellow light Major pigment in almost all photoautotrophs  Chlorophyll   b Absorbs red-orange, some blue Reflects green, some blue  Carotenoids     Absorb blue-violet, blue-green light Reflect red, orange, yellow light Give color to many flowers, fruits, vegetables Color leaves in Autumn  Anthocyanins     Absorb green, yellow, some orange light Reflect red, purple light Cherries, many flowers Color leaves in Autumn  Phycobilins    Absorb green, yellow, orange light Reflect red, blue-green light Some algae & bacteria  Pigment  absorbs light of specific wavelentgh Corresponds to energy of photon  Electron absorbs energy from photon  Energy boosts electron to higher level  Electron then returns to original level  When it returns, emits some energy (heat or photon)  Stage    Light energy converted to bond energy of ATP Water molecules split, helping to form NADPH Oxygen atoms escape  Stage  1 (Light-Dependent) 2 (Light-Independent) ATP energy used to synthesize glucose & other carbohydrates  Occurs in thylakoids  Electrons transfer light energy in electron transport chain  Electron transfers pump H+ into inner thylakoid compartment  Repeats, building up concentration and electric gradients  H+ can only pass through channels inside ATP Synthase  Ion flow through channel makes protein turn, forcing Phosphate onto ADP  Electrons continue until bonding NADP+ to form NADPH  NADPH used in next part of cycle  CO2 in air attaches to rubisco (RuBP)  Splits to form PGA  PGA gets phosphate from ATP, then H+ and electrons from NADPH  Forms PGAL  Two PGAL combine to form glucose plus phosphate group  Some PGAL recycles to form more RuBP  Takes 6 “turns” of cycle to form one glucose molecule  6 CO2 must be fixed and 12 PGAL must form to produce one glucose molecule and keep the cycle running *(G3P = PGAL)  Stomata    Close when hot & dry Keeps water inside Prevents CO2 & O2 exchange  Basswood, beans, peas, evergreens  3-Carbon PGA is first stable intermediate in Calvin-Benson cycle  Stomata close, O2 builds up  Increased O2 levels compete w/ CO2 in cycle  Rubisco attaches oxygen, NOT carbon to RuBP  This yields 1 PGA rather than 2  Lowers sugar production & growth of plant  12 “turns” rather than 6 to make sugars  Better adapted to cold & wet  Corn, tropical plants  Also close stomata on hot, dry days  Pumps carbon through cycles in 2 cells   Mesophyll cells: create 4-carbon molecule (oxaloacetate) Bundle-sheath cells: take 4-carbon molecule (malate), releases CO2 to Calvin-Benson cycle  This allows CO2 to remain high for C-B cycle  Requires 1 more ATP than C3, but less water lost & more sugar produced  Adapted to higher light & temp, lower water  Desert plants (cactus)  Crassulcean Acid Metabolism  Opens stomata at night, uses C4 cycle  Cells store malate & organic acids  During day when stomata close, malate releases CO2 for C-B cycle