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volume 2 - HotNews
volume 2 - HotNews

volume 2 - PianetaChimica
volume 2 - PianetaChimica

... effort to preserve the original text, the quantities and units have been used that are not SI. There were some problems with the presentation of the solutions of practical tasks, because most of the relatively simple calculations were based on the experimental results of contestants. Moreover, the p ...
Study Guide Chapter 10: An Introduction to Chemistry
Study Guide Chapter 10: An Introduction to Chemistry

... 5. If a calculation calls for you to convert from an amount of one substance in a given chemical reaction to the corresponding amount of another substance participating in the same reaction, it is an equation stoichiometry problem. 7. For some chemical reactions, chemists want to mix reactants in am ...
Chapter 10 Chemical Calculations and Chemical Equations
Chapter 10 Chemical Calculations and Chemical Equations

Chapter 8 PowerPoint - Southeast Online
Chapter 8 PowerPoint - Southeast Online

Copyright 2010 Scott R
Copyright 2010 Scott R

... Na(H3BNMe2BH3), in tetrahydrofuran produces the new complex Th(H3BNMe2BH3)4. The thorium center forms bonds with fifteen hydrogen atoms; accordingly, this is the first example of a fifteen-coordinate atom of any kind. As determined by both single crystal X-ray and single crystal neutron diffraction ...
Chemical Redox Agents for Organometallic
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Chemical Redox Agents for Organometallic

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COMPARATIVE EVALUATION OF TCF BLEACHED

... spectrometer, 5.7 kHz rotation frequency, crosspolarization time lms, time of repetition 3 s). TEM-investigations to study the fibrillar architecture were carried out by the group of Fink at Fraunhofer IAP, Teltow, Germany. Filter#ability of viscose was determined according to Treiber [ 121. ...
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4134gdisk doc..4134gdisk chapter .. Page501

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... 4.102 The statement of the problem indicates what reactions take place: H2S + O2 → SO2 + H2O. H and S are balanced; give O a coefficient of 3/2 to balance O, then multiply through by 2 to clear fractions: 2 H2S + 3 O2 → 2 SO2 + 2 H2O SO2 + H2S → S + H2O. H is already balanced; give H2S and H2O coeff ...
Fundamental Equilibrium Concepts
Fundamental Equilibrium Concepts

... value for Kc indicates that equilibrium is attained only after the reactants have been largely converted into products. A small value of Kc—much less than 1—indicates that equilibrium is attained when only a small proportion of the reactants have been converted into products. Once a value of Kc is k ...
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REVIEWS Environmental remediation by photocatalysis R. Vinu AND Giridhar Madras

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Support Material

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Synthetic Organic Chemistry - Name

... Fig.1 Structure of (LiC2H5)4 with tetrahedral geometry NMR studies also indicate that methyl lithium retains the tetrameric solid state structure in solution. The structures of (Li-R)4 units i.e tetrameric depicted by X2 ...
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VOLUME 3 - ICHO 41-45 _opravené_

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Mole-mole factor

... Limiting Reactant, Theoretical Yield, and Percent Yield • Chemical reactions with two or more reactants will continue until one of the reactants is used up (consumed) • If one of the reactants is used up, the reaction will stop because there is not enough of the other reactant to react with it • Th ...
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The Chemistry and Applications of Metal

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Organic Chemistry with a Biological Emphasis Volume I

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Late Transition Metal Amido Complexes: Electronic

content - Thesis Scientist
content - Thesis Scientist

1 2 3 4 5 ... 53 >

Supramolecular catalysis



Supramolecular catalysis is not a well-defined field but it generally refers to an application of supramolecular chemistry, especially molecular recognition and guest binding, toward catalysis. This field was originally inspired by enzymatic system which, unlike classical organic chemistry reactions, utilizes non-covalent interactions such as hydrogen bonding, cation-pi interaction, and hydrophobic forces to dramatically accelerate rate of reaction and/or allow highly selective reactions to occur. Because enzymes are structurally complex and difficult to modify, supramolecular catalysts offer a simpler model for studying factors involved in catalytic efficiency of the enzyme. Another goal that motivates this field is the development of efficient and practical catalysts that may or may not have an enzyme equivalent in nature.A closely related field of study is asymmetric catalysis which requires molecular recognition to differentiate two chiral starting material or chiral transition states and thus it could be categorized as an area of supramolecular catalysis, but supramolecular catalysis however does not necessarily have to involve asymmetric reaction. As there is another Wikipedia article already written about small molecule asymmetric catalysts, this article focuses primarily on large catalytic host molecules. Non-discrete and structurally poorly defined system such as micelle and dendrimers are not included.
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