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Fundamentals of Chemical Engineering Thermodynamics
Fundamentals of Chemical Engineering Thermodynamics

... plants and refrigeration/liquefaction systems. This is the part of the course that most directly relates to processes discussed in capstone design and justifies the “Chemical Engineering” in the title of the book. It is one of the longer chapters, with several examples and end-of-chapter problems. Th ...
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Thermal radiation



Thermal radiation is electromagnetic radiation generated by the thermal motion of charged particles in matter. An object with a temperature greater than absolute zero emits thermal radiation. When the temperature of the body is greater than absolute zero, interatomic collisions cause the kinetic energy of the atoms or molecules to change. This results in charge-acceleration and/or dipole oscillation which produces electromagnetic radiation, and the wide spectrum of radiation reflects the wide spectrum of energies and accelerations that occur even at a single temperature.Examples of thermal radiation include the visible light and infrared light emitted by an incandescent light bulb, the infrared radiation emitted by animals and detectable with an infrared camera, and the cosmic microwave background radiation. Thermal radiation is different from thermal convection and thermal conduction—a person near a raging bonfire feels radiant heating from the fire, even if the surrounding air is very cold.Sunlight is part of thermal radiation generated by the hot plasma of the Sun. The Earth also emits thermal radiation, but at a much lower intensity and different spectral distribution (infrared rather than visible) because it is cooler. The Earth's absorption of solar radiation, followed by its outgoing thermal radiation are the two most important processes that determine the temperature and climate of the Earth.If a radiation-emitting object meets the physical characteristics of a black body in thermodynamic equilibrium, the radiation is called blackbody radiation. Planck's law describes the spectrum of blackbody radiation, which depends only on the object's temperature. Wien's displacement law determines the most likely frequency of the emitted radiation, and the Stefan–Boltzmann law gives the radiant intensity.Thermal radiation is one of the fundamental mechanisms of heat transfer.
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