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Alcohols and Carbonyls
Alcohols and Carbonyls

... Homologous series CnH2n+1OH Ethanol and naming alcohols Different types of Alcohol Structures Oxidation and Dehyrdation of Alcohols Manufacture and uses of Ethanol Aldehydes and Ketones Methanol and steam reforming ...
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... The textile industry produces large quantities of effluents that contain significant concentrations of organic matter. The coloured waste water is directly discharged into the rivers and other water ways. Traditional methods like adsorption on activated carbon, liquid-liquid extraction, ion-exchange ...
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... between nitromethane and either aromatic or aliphatic aldehydes at 35 8C within about 24 h to produce nitroaldols 8 (R’ = H) in yields in the 56 to 90 % range and up to 93 % ee. Zinc-based catalysts are especially interesting because they might be compatible with aqueous systems in the light of the ...
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... by iron complexes of porphyrin and non-porphyrin ligands.12,13 Most significantly, the alkane hydroxylation by 2 was found to be highly stereospecific. In the hydroxylation of cis-1,2-dimethylcyclohexane,3b,13,14 (1R,2R or 1S,2S)-1,2-dimethylcyclohexanol, the tertiary alcohol with the methyl groups ...
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... base (H2SO4, H3PO4). To favour SN1 over E1, use a good nucleophile. •To favour E2 over SN2, use a strong, bulky non-nucleophilic base. To favour SN2 over E2, use good nucleophiles that are relatively weak bases. •It is important to keep in mind that although you might choose reaction conditions that ...
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... molecules that have the same chemical formula and structural backbone, but with a different arrangement of atoms in space • Cis isomer: a stereoisomer in which the groups of interest are located on the same side • Trans isomer: a stereoisomer in which the groups of interest are located on opposite s ...
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Cracking (chemistry)



In petroleum geology and chemistry, cracking is the process whereby complex organic molecules such as kerogens or heavy hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon-carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of a large alkane into smaller, more useful alkanes and alkenes. Simply put, hydrocarbon cracking is the process of breaking a long-chain of hydrocarbons into short ones. More loosely, outside the field of petroleum chemistry, the term ""cracking"" is used to describe any type of splitting of molecules under the influence of heat, catalysts and solvents, such as in processes of destructive distillation or pyrolysis. Fluid catalytic cracking produces a high yield of petrol and LPG, while hydrocracking is a major source of jet fuel, Diesel fuel, naphtha, and again yields LPG.
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