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Chemistry - Sanskriti School
Chemistry - Sanskriti School

... State the law of multiple proportion and explain it with the help of an example. ...
Unit 8: Reactions
Unit 8: Reactions

... 3. Double Replacement: A solution reaction in which the positive ion of one compound combines with the negative ion of the other compound to form a precipitate, and the other ions remain dissolved in solution. 4. Law of Conservation of Charge: Charge may not be created or destroyed by physical or ch ...
Activation of Alcohols Toward Nucleophilic Substitution: Conversion
Activation of Alcohols Toward Nucleophilic Substitution: Conversion

... and molecular biology. The alkyl halides have been utilized in the synthesis of many effective drugs. They are useful in nanomaterial fabrication and nanotechnologies.2 Halogenated compounds also play a significant role in organic synthesis. They react with nucleophiles to give the corresponding pro ...
Date: 16 / 01 / 2014 - Qatar University QSpace
Date: 16 / 01 / 2014 - Qatar University QSpace

... process. One of the objectives of this project is to develop catalysts with high performance. CuZSM-5 and Cu-Beta zeolite based catalysts were prepared using Ion Exchange (IE) method. A series of experiments were carried out to study the variation of preparation parameters such as support type, temp ...
mod-5-revision-guide-4-transition-metals
mod-5-revision-guide-4-transition-metals

... Following the reaction rate This can be done by removing samples at set times and titrating to work out the concentration of MnO 4- . It could also be done by use of a spectrometer measuring the intensity of the purple colour. This method has the advantage that it does not disrupt the reaction mixtu ...
Final Exam - Dawson College
Final Exam - Dawson College

... By recording the reaction rate of several experiments at different temperatures, the following graph based on the linear form of the Arrhenius equation is obtained. Arrhenius plot for the determination of the activation energy for the reaction of iodide with peroxydisulfate ...
Problem 5. Inorganic chains and rings
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... carbon honeycomb layers (Fig. 1a) are decorated with several types of oxygen containing functional groups. A net molecular formula of GO is СОXНY, where X and Y depend on the method of oxidation. In recent years GO has attracted much attention as a promising precursor of graphene, the most famous tw ...
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... solid surface of TiO2 particles and oxidized under UV illumination in the aqueous phase. Experiments were conducted under different reaction conditions of CH3SH loading, TiO2 dosage, and pH. The reaction kinetics of CH3SH reduction indicates that the pH of the reaction solution greatly influences th ...
CHE 110 Dr. Nicholas Bizier Office DS 337b email
CHE 110 Dr. Nicholas Bizier Office DS 337b email

... Lysine is an amino acid which has the following elemental composition: C, H, O, N. In one experiment, 2.175 g of lysine was combusted to produce 3.94 g of CO2 and 1.89 g H2O. In a separate experiment, 1.873 g of lysine was burned to produce 0.436 g of NH2. The molar mass of lysine is 150 g/mol. Dete ...
SCH4U Exam Review
SCH4U Exam Review

... an equilibrium mixture of these gases contained 0.280 M NH3 and 0.00840 M N2. What was the concentration of H2 in the mixture? ANS: 0.53 6. At high temperature, 0.500 mol of HBr was placed in a 1.00 L container and allowed to decompose according to the reaction 2HBr(g)  H2 (g) + Br2 (g). At equilib ...
Role of Pt-precursor on the performance of Pt/BaCO3/Al2O3·NOx
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NCERT Solution - Mywayteaching
NCERT Solution - Mywayteaching

... (i) Elements of group 16 have six valence electrons each. The general electronic configuration of these elements is ns2 np4, where n varies from 2 to 6. (ii) Oxidation state: ...
Chapter 8 and 9
Chapter 8 and 9

... Lysine is an amino acid which has the following elemental composition: C, H, O, N. In one experiment, 2.175 g of lysine was combusted to produce 3.94 g of CO2 and 1.89 g H2O. In a separate experiment, 1.873 g of lysine was burned to produce 0.436 g of NH2. The molar mass of lysine is 150 g/mol. Dete ...
Chemical Reactions
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... oxygen simply bounce off one another unchanged. However, at higher temperatures, the molecules collide at greater speeds, and therefore with greater energy. Atomic theory suggests that in such a collision, the repulsive forces of the electrons in the two molecules could be overcome. In some collisio ...
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... particular, the synthesis of [C4Źmim]PF6 (Scheme I) is readily accomplished using water as the only reaction solvent. The synthesis relies on the fact that this ionic liquid is immiscible with water and, therefore, is easily isolated by using a separatory funnel or removing the upper aqueous layer w ...
honors chemistry harvard-westlake second semester final exam
honors chemistry harvard-westlake second semester final exam

... 10. The hybrid orbitals of the carbon atom in methane, CH4 , are called a. sp b. sp2 c. sp3 d. sp4 11. Of the following molecules, all of which have polar bonds, the non-polar molecule is a. HCl (linear) b. H2O (v-shaped) c. NH3 (trigonal pyramid) d. CCl4 (tetrahedron) 12. For which of the following ...
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Exam - Vcaa

... Some commercially available remedies disrupt ionic interactions between the side chains on amino acid residues. These products most likely disrupt the protein’s A. primary structure only. B. secondary structure only. C. tertiary structure only. D. primary, secondary and tertiary structures. ...
Oxidative Alihatic Carbon-Carbon Bond Cleavage Reactions
Oxidative Alihatic Carbon-Carbon Bond Cleavage Reactions

... low temperatures and pressures, and using earth-abundant elements as reagents and catalysts. With these points in mind, nature provides an ideal model framework, carrying out its chemistry at ambient temperature and pressure. Enzymes that cleave C-C bonds by a dioxygenolytic pathway have been our fo ...
chapter twenty-one transition metals and coordination chemistry
chapter twenty-one transition metals and coordination chemistry

... No; both the trans or the cis forms of Co(NH3)4Cl2+ have mirror images that are superimposable. For the cis form, the mirror image only needs a 90Ε rotation to produce the original structure. Hence, neither the trans nor cis forms are optically active. ...
chapter 4 - reactions in solution
chapter 4 - reactions in solution

... Oxidizing agent- reactant that gains electrons; it contains the element being reduced; Reducing agent - reactant that loses electrons; it contains the element being oxidized. An oxidation-reduction (redox) reaction is an electron transfer reaction. Determining Oxidation-Reduction Reactions The oxida ...
COURSE  STRUCTURE
COURSE STRUCTURE

... Pauli’s Exclusion Principle : ‘‘No two electrons in an atom can have the same set of four quantum numbers.’’ Two electrons can have same values for n, l and ml provided their spins are opposite (ms is different). Therefore an orbital can have at the most two electrons if they have opposite spins. Hu ...
+ 2 H2O(l Ca(OH)2 aq)
+ 2 H2O(l Ca(OH)2 aq)

... c) Sulfur dioxide, SO2, is a nonmetal oxide that reacts with oxygen, O2, to form the higher oxide, SO3. Δ 2 SO (g) 2 SO2(g) + O2(g) ── ...
Amines - ncert
Amines - ncert

... reaction. Thus, only a small amount of hydrochloric acid is required to initiate the reaction. 2. Ammonolysis of alkyl halides You have read (Unit 10, Class XII) that the carbon - halogen bond in alkyl or benzyl halides can be easily cleaved by a nucleophile. Hence, an alkyl or benzyl halide on reac ...
KEY
KEY

... 3. there is the same amount of ammonia present as there was originally. 4. the nitrogen is used up completely. Explanation: LeChatelier’s Principle states that if a change occurs in a system at equilibruim, the system responds to relieve the stress and reach a new equilibrium. Here, the number of mo ...
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Photoredox catalysis



Photoredox catalysis is a branch of catalysis that harnesses the energy of visible light to accelerate a chemical reaction via a single-electron transfer. This area is named as a combination of ""photo-"" referring to light and redox, a condensed expression for the chemical processes of reduction and oxidation. In particular, photoredox catalysis employs small quantities of a light-sensitive compound that, when excited by light, can mediate the transfer of electrons between chemical compounds that otherwise would not react. Photoredox catalysts are generally drawn from three classes of materials: transition-metal complexes, organic dyes and semiconductors. While each class of materials has advantages, soluble transition-metal complexes are used most often.Study of this branch of catalysis led to the development of new methods to accomplish known and new chemical transformations. One attraction to the area is that photoredox catalysts are often less toxic than other reagents often used to generate free radicals, such as organotin reagents. Furthermore, while photoredox catalysts generate potent redox agents while exposed to light, they are innocuous under ordinary conditions Thus transition-metal complex photoredox catalysts are in some ways more attractive than stoichiometric redox agents such as quinones. The properties of photoredox catalysts can be modified by changing ligands and the metal, reflecting the somewhat modular nature of the catalyst.While photoredox catalysis has most often been applied to generate known reactive intermediates in a novel way, the study of this mode of catalysis led to the discovery of new organic reactions, such as the first direct functionalization of the β-arylation of saturated aldehydes. Although the D3-symmetric transition-metal complexes used in many photoredox-catalyzed reactions are chiral, the use of enantioenriched photoredox catalysts led to low levels of enantioselectivity in a photoredox-catalyzed aryl-aryl coupling reaction, suggesting that the chiral nature of these catalysts is not yet a highly effective means of transmitting stereochemical information in photoredox reactions. However, while synthetically useful levels of enantioselectivity have not been achieved using chiral photoredox catalysts alone, optically-active products have been obtained through the synergistic combination of photoredox catalysis with chiral organocatalysts such as secondary amines and Brønsted acids.
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