Survey
* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project
* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project
IGINIBI GNB TECHNOLOGIES TM VALUE ENGINEERING CENTER TEST REPORT Date: July 16, 1998 By: Joseph Szymborski, Director of Product Support Re: Solartech Can-PULSE Charging Device [now the Canadus battery energizer] 1. OBJECTIVE The purpose of this test was to evaluate the Solartech Products Ltd “Can-PULSE” device which is claimed by its supplier to “… prevent battery deterioration by maintaining the electrochemical balance within the battery and thus eliminating the sulfate build-up”. The objectives of the experiments conducted were (i) to determine the general theory of operation of the device, (ii) to determine if the device causes any negative effects on a fully charged battery, and (iii) to determine if the device provides any positive effects in recovering sulfated batteries. The intention of these tests was to assess if any damage would result to GNB’s batteries as the result of applying this device, and to identify potential benefits which could be realized from using the device in specific applications. This Test Report should not be considered as a testimonial for or against this product. 2. BACKGROUND The Value Engineering Center received a request from Transportation Products Sales Co. to evaluate the Solartech Can-PULSE device as the result of inquiries made from several railroads which they serve and provide GNB batteries. Personnel from these railroads have indicated to TPS that they have experienced good results using the Solartech Can-PULSE device on company vehicles and even some diesel locomotive starting batteries. Most of this experience however was undocumented and developed under uncontrolled conditions as might be expected in the field, and thus TPS asked the Value Engineering Center to evaluate the device. A Can-PULSE Charge Partner for use on 12-volt automotive type batteries and a 12-volt CanPULSE Motive Power Battery Maintenance System was provided by Solartech. In addition, they submitted product data sheets and several technical articles which discussed how the device works on lead-acid batteries to prevent the onset of sulfation and to recover batteries which had become sulfated as the result of misuse and inadequate charging. The technical articles showed electron microscope photographs of battery plates which were sulfated and those which had been recovered following a period of regular charging with the Can-PULSE device. The scope of this project was to assess the operation and effectiveness of the Can-PULSE device on VRLA batteries manufactured by GNB in the short-term. It was not the intention of these tests to determine long-term effects on battery lifetime. 1 IGINIBI GNB TECHNOLOGIES TM VALUE ENGINEERING CENTER 3. EXPERIMENTAL RESULTS Two separate experiments were conducted to evaluate the Can-PULSE device. The first was to assess the interaction of the device with a fully charged battery. This test was conducted to determine if any obvious deleterious effects could be anticipated by the use of the device. The second set of experiments was conducted to determine if the device would be useful in recovering a battery which had been allowed to deteriorate because of an extended period of storage without any charging. This test would determine if there was any validity to CanPULSE’s claims. 3.1 Experimental Setup The Can-PULSE device itself is not a battery charger. The device works in conjunction with conventional battery chargers to provide a proprietary pulse to the battery which is stated to prevent the formation of lead sulfate on the battery’s plates. The device connects across the terminals of the battery with one lead from the device going to the positive terminal and the other lead to the negative terminal of the battery. The device does not interfere with or require any modifications to the conventional charger used with the battery. The device is activated only after the battery reaches 14 volts (2.33 volts per cell). The device does not draw any current from the battery while the battery is on open circuit stand or on charge at a voltage less than 14 volts. An LED on the device indicates when the device is activated. The device was connected to a fully charged GNB Sprinter S12V370 Valve-Regulated LeadAcid battery. This is a “sealed” 12-volt monoblock battery used primarily in power standby applications. This battery was selected because its VRLA design makes this type of battery more sensitive to charging conditions than a conventional flooded type battery. The charger selected to be used for these experiments was a Schumacher SE-50-MA-2 unit with a switch selectable 2-amp or 10-amp output capability. Charging current was measured using a 10-amp / 100-millivolt shunt connected in series with the charger output. The waveform of the charging current was monitored using a Hewlett-Packard Model 54615B oscilloscope. 3.2 Interaction With A Fully Charged Battery There was no change in the battery’s open circuit voltage when the device was connected to the battery’s terminals, indicating that there was no parasitic current drain on the battery. The battery was charged using the Schumacher charger both with the device connected and without the device connected. The only noticeable difference relative to the battery when the device was connected was a change in the charge current waveform. Without the device, the charger’s output exhibited a small current ripple with an occasional random current spike. When the device was connected to the battery, the charge current exhibited a significant 2 IGINIBI GNB TECHNOLOGIES TM VALUE ENGINEERING CENTER increase both in the number of high current spikes, and in the amplitude of the high current spikes. The current spikes were extremely short in duration and showed as a single line on the oscilloscope even with the scope set at its fastest time base. With the scope, both positive going current spikes (i.e., charging) and negative going spikes (i.e., discharging) were observed. There was no observable difference in the voltage of the battery when measured using a digital voltmeter with or without the device, and the baseline current from the charger was unchanged. There was no noticeable temperature rise of the battery with the device connected even after being overcharged at the charger’s finish voltage for several hours. Although it was possible to detect a significant number of high current charge and discharge pulses of the order of 20 – 30 amps, the duration of these pulses was short enough so as to not cause a significant perturbation of this fully charged battery. As a result of these observations, it is my opinion that when used in conjunction with a properly adjusted charger, the Can-PULSE device should not cause the battery to be excessively overcharged or generate excessive heat which could be damaging to the battery. No tests were run where the battery was continuously charged for an extended period of time with the device connected. The device seems to be more appropriately used in applications with intermittent charging rather than a continuous “float” charge, or in applications where the battery is routinely subjected to a discharge which removes a significant portion of the battery’s capacity. 3.3 Tests With A Sulfated Battery To determine if the device could be effective in recovering a “sulfated” battery, an experiment was conducted using two old 12-volt, 50Ah VRLA batteries which had been in storage for several years. The initial open circuit voltage of these 12-volt batteries was measured at 6.40 and 6.66 volts. The impedance of the batteries was measured using a Hewlett-Packard milliohmeter at 5.4 and 5.2 kOhms respectively. When connected to a 5 amp discharge load, battery voltage immediately collapsed to 0 volts. For all practical purposes, these batteries were completed “dead”. One of the batteries was connected to the Schumacher charger without the Can-PULSE device and allowed to be charged for a period of 20 hours. Charge current initially was less than 0.5 amps, but increased to about 1 amp for most of the charge period. At the end of this charge period, the battery’s on-charge voltage was 13.8 volts (2.30 volts per cell). The battery’s open circuit voltage measured 12.32 volts; however, the battery’s voltage immediately collapsed to 0 volts when connected to a 5-amp discharge load. This part of the experiment shows that even though there are indications that the battery may be 3 IGINIBI GNB TECHNOLOGIES TM VALUE ENGINEERING CENTER charging, such as a current flow and a reasonable open circuit voltage at the end of charge, the charge was useless in converting the battery’s discharged (and presumably sulfated) active material to a fully charged condition. The second battery was then charged using the same Schumacher charger but with the CanPULSE device connected across the battery’s terminals. Once again, the charge period was 20 hours. This time the current immediately rose to greater than 2 amps and was maintained at 2 – 3 amps throughout the charge. Open circuit voltage of the battery after charge was 12.47 volts; its resistance was measured at 0.81 Ohms. Although this resistance is still greater than what would be expected for this size battery (about 5 milliohms), it is far less than the initial reading of 5.37 kOhms. When connected to the 5-amp discharge load, the battery operated for 45.9 minutes. The first battery was then again recharged, this time using the Can-PULSE device. The charge current rose immediately into the 2 – 3 amp range and the battery voltage rose to greater than 14 volts. After 20 hours of charging, this battery had an open circuit voltage of 12.76 volts and a resistance of 0.197 Ohms. Although this is still almost 40 times greater than a “good” battery, it is almost 25,000 times less than the initial resistance measured on this battery. When connected to the 5-amp discharge load, the battery operated for 105 minutes, when just the previous cycle it immediately collapsed to zero volts. The two old batteries tested were still far below the performance of a “good” battery, but the improvements which they did make were significant considering their initial condition. It is safe to say that the charge given to the batteries with the Can-PULSE device connected was much more beneficial in recovering the batteries than the charge using just the conventional charger. Whether the batteries would fully recover is not known; however improvements were made. 4. SUMMARY AND CONCLUSIONS The Solartech Can-PULSE Charge Partner was tested on both fully charged and badly sulfated VRLA batteries. The device appeared not to induce any detrimental effects such as increased voltage, increased charging current or increased heating on the “good”, fully charged battery. On the other hand, when connected to a heavily sulfated battery, it appeared to improve charge acceptance of the battery, significantly reduce its internal resistance, and partially recover the battery so that it could operate at acceptable voltages under discharge load. Based on these test results and the data provided by Solartech, it is my opinion that the Can-PULSE device will not harm a “good” battery and can actually help in preventing a battery from sulfating due to inadequate charge or abusive operation. (Reprinted with permission of Joseph Szymborski and GNB. Emphasis added.) 4