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THE EARTH THROUGH TIME TENTH EDITION H A R O L D L. L E V I N © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. 1 CHAPTER 3 Time and Geology © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. FINDING THE AGE OF ROCKS: RELATIVE VERSUS ACTUAL DATING The science that deals with determining the ages of rocks is called geochronology. Dating rocks started some 400 years ago with Nicholas Steno. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. METHODS OF DATING ROCKS 1. Relative dating - Using fundamental principles of geology (Steno's Laws, Fossil Succession, etc.) to determine the which rocks are older and which are younger. In other words, determine the sequences of events without regard to a specific date. 2. Actual (Absolute) dating - Quantifying the date of the rock in years before the present. This is done primarily by radiometric dating (or detailed analysis of the breakdown of radioactive elements within the rocks over time). © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. GEOLOGIC TIME SCALE The geologic time scale has been determined over many years of research through relative dating, correlation, examination of fossils, and radiometric dating. Boundaries on the time scale are placed where important changes occur in the fossil record, such as extinction events. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. GEOCHRONOLOGIC UNITS The geologic time scale is divided into a number of units of differing sizes. From the largest units to the smaller units, they are: •Eons > Eras > Periods > Epochs These units are geochronologic units or time units. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. THE MODERN GEOLOGICAL TIME SCALE Word modifiers: pro - before phanero - evidence paleo - ancient meso – middle neo – new ceno – resent eo – dawn zoon - life © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. FIGURE 3-1 Geologic Time Scale. EONS In order from oldest to youngest: Hadean Eon—This is an informal time unit referring to the earliest Earth history where no rock record has been preserved. Archean Eon—"ancient or archaic“—oldest rocks on Earth (~4 billion to 2.5 billion years ago) Proterozoic Eon—"beginning life" (2.5 billion to 542 million years ago) Phanerozoic Eon—"visible life" (542 million years ago to present) © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. PRECAMBRIAN The Archean and Proterozoic are together referred to as the Precambrian, meaning "before the Cambrian Period." The Precambrian encompasses 87% of geologic history. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. ERAS Phanerozoic Eon is divided into three Eras Youngest Oldest Cenozoic Era—"recent life" (such as mammals) Mesozoic Era—"middle life" (such as dinosaurs) Paleozoic Era—"ancient life" (such as trilobites) PERIODS Eras are divided into periods. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. PALEOZOIC ERA Youngest Permian Period Carboniferous Period— (split into Mississippian & Pennsylvanian Periods in the United States) Devonian Period Silurian Period Ordovician Period Cambrian Period Oldest © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. MESOZOIC ERA Youngest Oldest Cretaceous Period Jurassic Period Triassic Period © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. CENOZOIC ERA Youngest Oldest Quaternary Period Neogene Period Paleogene Period The former Tertiary Period is now split into two. On maps and in publications prior to 2003, you will see the two periods of the Cenozoic Era listed as: Quaternary Period Tertiary Period (oldest) Periods are subdivided into epochs. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. EPOCHS OF THE CENOZOIC ERA Youngest Quaternary Period Neogene Period Pliocene Epoch Miocene Epoch Paleogene Period Oldest Holocene Epoch Pleistocene Epoch Oligocene Epoch Eocene Epoch Paleocene Epoch © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. CHRONOSTRATIGRAPHIC UNITS Chronostratigraphic units represent the actual rocks deposited or formed during a specific time interval. Sometimes called "time-rock units." Units include: Eonothem (all rocks corresponding to a given eon) Erathem (all rocks corresponding to a given era) System (all rocks corresponding to a given period) Series (all rocks corresponding to a given epoch) Stage (all rocks corresponding to a particular age) © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. PERIODS AND SYSTEMS Geochronologic units (time units) have the same names as their chronostratigraphic units (time-rock units). For example, Cambrian Period is a time unit, and Cambrian System is a time-rock unit. The rocks of the Cambrian System were deposited during the period called Cambrian. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. ACTUAL GEOLOGIC TIME: CLOCKS IN THE ROCKS Early Attempts to determine the age of the Earth: Biblical – October 23, 4004 BCE Evolution of Fossils – 80 million years Sedimentation deposition rates – Ranged from a million to over a billion years Ocean Salinity – 90 million years Cooling Rate – 24 to 40 million years © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. PRINCIPLES OF RADIOMETRIC DATING © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. REVIEW OF ATOMS Atom = smallest particle of matter that can exist as a chemical element. The structure of the atom consists of: Nucleus composed of protons (positive charge) and neutrons (neutral) Electrons (negative charge) orbit the nucleus Various subatomic particles © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. MODEL OF THE ATOM FIGURE 3-5 IONS Most atoms are electrically neutral, with the number of protons equaling the number of electrons in the nucleus. If there is an unequal number of protons and electrons, the atom has a charge (positive or negative), and it is called an ion. Negative (-) charged ion is an Anion Positively (+) charged ion is a Cation © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. ATOMIC NUMBER Atomic number of an atom = number of protons in the nucleus of that atom. Each element such as Carbon ( 6 protons) or Oxygen (8 protons) has its own unique number of protons in the atom. Example: The atomic number of uranium is 92. Uranium has 92 protons. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. MASS NUMBER & ISOTOPES Mass number is the sum of the number of protons plus neutrons in the nucleus. Example: Uranium-235 has 92 protons and 143 neutrons. The mass number may vary for an element, because of a differing number of neutrons. These are called isotopes. Example: Uranium-235 and Uranium-238 © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. ISOTOPES Some isotopes are unstable. They undergo radioactive decay, releasing particles and energy. Some elements have both radioactive and nonradioactive isotopes. Examples: carbon, potassium © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. WHAT HAPPENS WHEN ATOMS DECAY? Radioactive decay occurs by releasing subatomic particles and energy. The radioactive parent element is unstable and undergoes radioactive decay to form a stable daughter element. Example: Uranium, the parent element, undergoes radioactive decay, releases subatomic particles and energy, and through a series of steps decays to form the stable daughter element, lead. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. RADIOACTIVE PARENT ISOTOPES & THEIR STABLE DAUGHTER PRODUCTS Radioactive Parent Isotope Stable Daughter Isotope Potassium-40 Argon-40 Rubidium-87 Strontium-87 Thorium-232 Lead-208 Uranium-235 Lead-207 Uranium-238 Lead-206 Carbon-14 Nitrogen-14 © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. RADIOACTIVE DECAY OF URANIUM FIGURE 3-6 Radioactive decay series. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. SUBATOMIC PARTICLES AND RADIATION RELEASED BY RADIOACTIVE DECAY Alpha particles—atomic weight = 4; atomic number = (The same as the nucleus of a helium atom. Has + charge of 2.) Beta particles—an electron that is released when a neutron splits into a proton and an electron. (Like all electrons, the mass is negligible and there is a positive charge.) Gamma rays—electromagnetic waves much like x-rays, but higher frequency (Like all electromagnetic waves, including light, there is no charge mass associated this photon or "particle.") © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. or RADIOACTIVE DECAY Naturally-occurring radioactive materials break down into other materials at known rates. This is known as radioactive decay. Many radioactive elements can be used as geologic clocks. Each radioactive element decays at its own constant rate. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. DECAY RATES ARE UNIFORM Radioactive decay occurs at a constant or uniform rate. The rate of decay is not affected by changes in pressure, temperature, or other chemicals. As time passes, the number of parent atoms decreases and the number of daughter atoms increases at a known rate. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. MASS SPECTROMETER & DECAY RATES The quantities and masses of atoms and isotopes are measured using an instrument called a mass spectrometer. The decay rates of the various radioactive isotopes are measured directly using a mass spectrometer. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. HALF-LIFE A half-life is the time it takes for one-half of the parent radioactive element to decay to a daughter product. Radioactive Parent Stable Daughter Half-life Potassium-40 Argon-40 1.25 billion yrs Rubidium-87 Strontium-87 48.8 billion yrs Thorium-232 Lead-208 14 billion years Uranium-235 Lead-207 704 million years Uranium-238 Lead-206 4.47 billion years Carbon-14 Nitrogen-14 5730 years © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. RATE OF DECAY FOR URANIUM-238 FIGURE 3-10 Rate of radioactive decay of uranium-238 to lead-206. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. RATE OF DECAY FOR POTASSIUM-40 FIGURE 3-12 Decay curve for potassium-40. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. ROCKS THAT CAN BE DATED Igneous rocks are best for age dating. When the magma cools and crystallizes, the newly formed crystals usually contain some radioactive elements, such as Potassium-40 or Uranium-238 that can be used for radiometric dating. As mineral forms it preferentially incorporates the parent and not the daughter. When the parent decays the daughter is trapped in the crystalline structure © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. MINERALS THAT CAN BE DATED Potassium-40 is found in these minerals: Potassium feldspar Muscovite Amphibole Uranium may be found in: Zircon Urananite Monazite Apatite Sphene © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. DATING SEDIMENTARY ROCKS If the sedimentary rock contains a mineral that formed at the same time as the rock formed, then it may be possible to use that mineral to obtain a radiometric age date. The sedimentary mineral glauconite contains potassium, and can be used for radiometric dating (employing the potassium-argon technique). © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. DATING SEDIMENTARY ROCKS The ages of sedimentary rocks and fossils are determined using both relative and absolute dating. Illustration “A” shows a shale layer sandwiched between two lava flows of know ages. The ages of the lava flows bracket the age of the shale. Illustration “B” shows a shale layer underlain by a lava flow and cross-cut by an igneous dike of FIGURE 3-8 Igneous rocks that have provided absolute radiogenic ages can known ages These ages bracket often be used to date sedimentary layers. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. the age of the shale. DATING FOSSILS The ages of fossils in a sequence of sedimentary rocks can be determined using both relative and absolute dating. FIGURE 3-9 The actual age of rocks that cannot be dated isotopically can sometimes be ascertained by correlation. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. GEOLOGIC TIME SCALE The geologic time scale is a composite vertical sequence representing all known rock units and their fossils, worldwide, in sequential order. Absolute ages of rocks have been determined through radiometric dating where possible. The geologic time scale provides a calibrated scale for determining the ages of rocks worldwide including their fossils. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. CARBON-14 DATING 1. Cosmic rays from the sun (mostly protons) strike atoms in the upper atmosphere resulting in the production of high energy neutrons. When one of these neutrons strikes a Nitrogen-14 atom in the atmosphere it causes a proton to be ejected and radioactive Carbon-14 forms. Carbon-14 then combines with oxygen to form radioactive carbon dioxide. FIGURE 3-14 Carbon-14 is formed from nitrogen in the atmosphere. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. CARBON-14 DATING 2. Living things are in equilibrium with the atmosphere, because radioactive carbon dioxide is absorbed and used by plants. The radioactive carbon dioxide gets into the food chain and thus the carbon cycle. All living things contain a constant ratio of Carbon-14 to Carbon-12 (about 1 in a trillion). FIGURE 3-14 Carbon-14 is formed from nitrogen in the atmosphere. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. CARBON-14 DATING 3. At death, Carbon-14 exchange ceases and any Carbon-14 in the tissues of the organism begins to decay to Nitrogen-14, and is not replenished by new Carbon-14. The change in the Carbon-14 to Carbon-12 ratio in fossil material is the basis for this kind of radiometric dating. FIGURE 3-14 Carbon-14 is formed from nitrogen in the atmosphere. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. CARBON-14 DATING The half-life is so short (5,730 years) that this method can only be used on materials less than 50,000 years old. Assumes that the rate of Carbon-14 production (and hence the amount of cosmic rays striking the Earth) has been constant over the past 50,000 years. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. RUBIDIUM-STRONTIUM METHOD Rubidium-87 expels a beta particle, it becomes Strontium-87. Strontium-86 isotope is present in the rock, but is not radioactive. Using a mass spectrometer, the ratio of 87Rb to 86Sr and the 87Sr to 86Sr ratios are determined for several samples. This is plotted on a graph and the line thus determined is called an isochron. The slope of the line permits computation of the age of the mineral crystals being studied. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. FIGURE 3-13 Whole-rock rubidium-strontium isochron for a set of samples of a Precambrian granite body exposed near Sudbury, Ontario. FISSION TRACK DATING Charged particles from radioactive decay pass through a mineral's crystal lattice and leave trails of damage in the crystal called fission tracks. These trails are due to the spontaneous fission (or radioactive decay) of the uranium nucleus. Useful in dating: Micas (up to 50,000 tracks per cm2) Other uranium-bearing minerals and natural glasses © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. FISSION TRACK DATING Procedure: Enlarge tracks by etching in acid (to view with light microscope)—or view them directly with electron microscope Count the etched tracks (or measure the density of such tracks in a given area of the crystal) The number of tracks per unit area is a function of age and uranium concentration. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. THE OLDEST ROCKS—METEORITES The oldest rocks that have been dated are meteorites. They date from the time of the origin of the solar system and the Earth, about 4.6 billion years old. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. THE OLDEST ROCKS—MOON Moon rocks have dates that range in age from 3.3 to about 4.6 billion years. The oldest Moon rocks are from the lunar highlands (lighter-colored areas on the Moon), and may represent the original lunar crust © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. THE OLDEST ROCKS—EARTH The oldest dates of Earth rocks are 4.36 billion-year-old detrital zircon grains in a sandstone in western Australia. These grains probably came from the weathering and erosion of 4.36 billion-yearold granite that must have been exposed at the time the sand grains were deposited. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. OTHER OLD EARTH ROCKS 1. 2. 3. 4. Southwestern Greenland (granite; 4.0 b.y.) Minnesota (metamorphic rocks; 4.0 b.y.) Northwest Territories, Canada (gneiss; 4.04 b.y.) Hudson Bay, northern Quebec (zircons; 4.28 b.y.) Still older rocks on Earth may remain to be found and dated using radiometric methods. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. WHY ARE EARTH ROCKS YOUNGER THAN METEORITES AND MOON ROCKS? The Earth is geologically active. The older rocks may have been eroded away or destroyed by tectonic forces. Older rocks may remain deeply buried under sedimentary rocks, or under mountain ranges. Older rocks may have been heated, metamorphosed, or melted, and their isotopes "reset" to the time of the later events of heating, metamorphism, or melting. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED. IMAGE CREDITS • FIGURE 3-1 Geologic Time Scale. Source: Harold Levin. • FIGURE 3-5 Model of an Atom. Source: Harold Levin. • FIGURE 3-6 Radioactive decay series. Source: Harold Levin. • FIGURE 3-10 Rate of radioactive decay of uranium-238 to lead-206. Source: Reprinted from Earth and Planetary Science Letters, by Steiger, R. and Jäger, E. Subcommission on geochronology: Convention on the use of decay constants in geo- and cosmochronology, 359-362, 1977, with permission from Elsevier. • FIGURE 3-12 Decay curve for potassium-40. Source: Harold Levin. • FIGURE 3-8 Igneous rocks that have provided absolute radiogenic ages can often be used to date sedimentary layers. Source: Harold Levin. • FIGURE 3-9 The actual age of rocks that cannot be dated isotopically can sometimes be ascertained by correlation. Source: Harold Levin. • FIGURE 3-14 Carbon-14 is formed from nitrogen in the atmosphere. Source: Harold Levin. FIGURE 3-13 Whole-rock rubidium-strontium isochron for a set of samples of a Precambrian granite body exposed near Sudbury, Ontario. Source: Harold Levin. © 2013 JOHN WILEY & SONS, INC. ALL RIGHTS RESERVED.