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SCOTTISH QUALIFICATIONS AUTHORITY – MAY 2012 CURRICULUM EVENTS – COURSE AIMS AND STRUCTURE SUBJECT: CHEMISTRY PURPOSE: The purpose of the Course is to develop learners’ curiosity, interest and enthusiasm for chemistry in a range of contexts. Th e key skills of scientific inquiry and investigation are integrated and developed throughout the Course. The relevance of chemistry is highlighted by the study of the applications of chemistry in everyday contexts. This will enable learners to become scientifically literate citizens, able to review the science -based claims they will meet. National 3 National 4 National 5 Higher COURSE AIMS The aims of the Course are to enable learners to: The main aims of this Course are to: The aims of this Course are for learners to: develop basic knowledge and understanding of chemistry develop an understanding of chemistry’s role in scientific issues and relevant applications of chemistry in society and the environment develop scientific inquiry and investigative skills develop scientific analytical thinking skills in a chemistry context develop the use of technology, equipment and materials, safely, in practical scientific activities develop problem solving skills in a chemistry context use scientific literacy in everyday contexts establish the foundation for more advanced learning in chemistry develop and apply knowledge and understanding of chemistry develop an understanding of chemistry’s role in scientific issues and relevant applications of chemistry in society and the environment develop scientific inquiry and investigative skills develop scientific analytical thinking skills in a chemistry context develop the use of technology, equipment and materials, safely, in practical scientific activities develop problem solving skills in a chemistry context use and understand scientific literacy, in everyday contexts, to communicate ideas and issues develop the knowledge and skills for more advanced learning in chemistry develop and apply knowledge and understanding of chemistry develop an understanding of chemistry’s role in scientific issues and relevant applications of chemistry, including the impact these could make in society and the environment develop scientific inquiry and investigative skills develop scientific analytical thinking skills in a chemistry context develop the use of technology, equipment and materials, safely, in practical scientific activities develop planning skills develop problem solving skills in a chemistry context use and understand scientific literacy, in everyday contexts, to communicate ideas and issues and to make scientifically informed choices develop the knowledge and skills for more advanced learning in chemistry develop skills of independent working The main aims of this Course are for learners to: develop and apply knowledge and understanding of chemistry develop an understanding of chemistry’s role in scientific issues and relevant applications of chemistry, including the impact these could make in society and the environment develop scientific inquiry and investigative skills develop scientific analytical thinking skills, including scientific evaluation, in a chemistry context develop the use of technology, equipment and materials, safely, in practical scientific activities, including using risk assessments develop planning skills develop problem solving skills in a chemistry context use and understand scientific literacy to communicate ideas and issues and to make scientifically informed choices develop the knowledge and skills for more advanced learning in chemistry develop skills of independent working STRUCTURE, ASSESSMENT AND HIERARCHIES Course Structure: 3 Units as follows: Chemical Changes and Structure Nature’s Chemistry Chemistry in Society Course Structure: 3 Units and Added Value Unit as follows: Chemical Changes and Structure Nature’s Chemistry Chemistry in Society Course Structure: 3 Units and Course Assessment as follows: Chemical Changes and Structure Nature’s Chemistry Chemistry in Society Course Structure: 4 Units and Course Assessment as follows: Chemical Changes and Structure Nature’s Chemistry Chemistry in Society Researching Chemistry National 3 Unit Outcomes National 4 National 5 Higher and Added Value Unit: Chemistry Assignment and Course Assessment: Question Paper and Assignment and Course Assessment: Question Paper and Assignment Unit Outcomes Unit Outcomes Unit Outcomes 1) Apply skills of scientific inquiry and draw on knowledge and understanding of the key areas of the Units to carry out an experiment/practical investigation 1) Apply skills of scientific inquiry and draw on knowledge and understanding of the key areas of the Units to carry out an experiment/practical investigation 1) Apply skills of scientific inquiry and draw on knowledge and understanding of the key areas of the Units to carry out an experiment/practical investigation 1) Apply skills of scientific inquiry and draw on knowledge and understanding of the key areas of the Units to carry out an experiment/practical investigation 2) Draw on knowledge and understanding of the key areas of the Units and apply scientific skills 2) Draw on knowledge and understanding of the key areas of the Units and apply scientific skills 2) Draw on knowledge and understanding of the key areas of the Units and apply scientific skills 2) Draw on knowledge and understanding of the key areas of the Units and apply scientific skills Transfer of evidence: Outcome 1 in one Unit may be Transfer of evidence: Outcome 1 in one Unit may be Transfer of evidence: Outcome 1 in one Unit may be Transfer of evidence: Outcome 1 in one Unit may be used as evidence of the achievement of Outcome 1 in the used as evidence of the achievement of Outcome 1 in the used as evidence of the achievement of Outcome 1 in the used as evidence of the achievement of Outcome 1 in the other Units of this Course. other Units of this Course. other Units of this Course. other Units of this Course. Key areas Chemical changes and Structure rates of reaction — indicators of chemical reactions chemical structure — elements, compounds and mixtures; chemical and physical properties of elements related to position in the periodic table; two-element compounds; chemical formulae (including prefixes) of two-element compounds acids and bases — concentrated vs dilute; pH scale and indicators; environmental impact of non-metal oxides; neutralisation reactions including naming of salts; uses of common neutralisation reactions Key areas Chemical changes and Structure rates of reaction — following the rate of a reaction atomic structure and bonding related to properties of materials — basic atomic structure including electron arrangement; covalent bonding as electron sharing and ionic bonding of electron transfer; physical properties of substances linked to bonding, chemical formulae of two element compounds; symbol equations from word equations energy changes of chemical reactions — recognising and uses of exothermic and endothermic reactions acids and bases — the effect of soluble oxides on the pH of water; soluble oxides and their environmental impact of non-metal oxide; uses of acids in food and drink and their impact on health; selection of chemicals for salt formation Key areas Chemical Changes and Structure rates of reaction — average rate of reaction calculated from graph to show change in rate as reaction progresses atomic structure and bonding related to properties of materials — nuclide notation. isotopes and relative atomic mass, ions and ionic bonding covalent molecular, covalent network and ionic lattices; physical properties of chemicals explained through bond; chemical and ionic formulae including group ions formulae and reaction quantities — balanced equations; gram formula mass, the mole, calculations relating mass, volume of solutions, concentration and moles acids and bases — dissociation of water into hydrogen and hydroxide ions; pH is related to the concentration of hydrogen and hydroxide ions in pure water, acids and alkalis; neutralisation titration Key areas Chemical Changes and Structure Controlling the rate — collision theory, reaction profiles, potential energy diagrams, activation energy, activated complex and enthalpy changes. Catalysts, reaction pathway, activation energy. Energy distribution diagrams showing effect of temperature changes on successful collisions. The effect of temperature on the reaction rate in terms of kinetic energy of particles. Periodicity — bonding and structure in first 20 elements, periodic trends and underlying patterns and principles, covalent radius, electro-negativity and trends in groups and periods. Structure and bonding — bonding continuum, polar covalent bonds, intermolecular and intramolecular forces and their role in determining a material's physical properties. Nature’s Chemistry fuels and energy: environmental impact of using different energy sources everyday consumer products: essential oils from plants — uses and identification, plants for food, oils and carbohydrates from plants, nutrients in plants plants to products: plants used to make everyday consumer products Nature’s Chemistry fuels — formation and extraction processes for crude oil; the use of fuels and their environmental impact on the carbon cycle, and alternative energy sources including biomass hydrocarbons — fractional distillation and cracking, straight chained alkanes (C1–C8), alkenes (C2–C8), their physical, chemical properties, general formulae, structural formulae and uses; unsaturated and saturated hydrocarbons Nature’s Chemistry homologous series — the study of cycloalkanes and branched chain alkanes and alkenes to include their physical, chemical properties, general formulae, systematic names, structural formulae, uses, and isomers everyday consumer products — uses of alcohols and carboxylic acids: to include their physical, chemical properties; for straight chain alcohols and carboxylic acids (C1–C8) general formulae, systematic naming, Nature’s Chemistry Esters, fats and oils — esters naming, structural formulae and uses. Fats and oils, esters condensation reactions. Saturated and unsaturated fats and oils. Melting points of oils and fats, through intermolecular bonding. Proteins — enzymes, amino acids, dietary proteins, condensation reaction to make proteins and amide link/peptide link. Digestion, enzyme hydrolysis. Chemistry of cooking — flavours in foods. Influence of National 3 Chemistry in Society properties of materials — testing the properties of materials and investigating their uses chemical analysis — environmental testing National 4 everyday consumer products — alcoholic drinks: sources and production, units in drinks and health issues, analysis of carbohydrates, Benedict’s and iodine solutions; solubility of carbohydrates; competing demands for carbohydrates as food or fuel plants to products — practical-based activity on products derived from plants which have enhanced everyday life National 5 structural formulae; manufacture of esters as a use of alcohols and carboxylic acids; uses of esters energy from fuels — energy calculations involving Eh = cm∆t (not per mole) calculations based on balanced equations Chemistry in Society Chemistry in Society metals — metallic bonding and resulting electrical conductivity; balanced ionic equations for reactions of metals, extraction of metals and reduction reactions; electrochemical cells including a non-metal electrode; reactions of metals — electrons flow, redox reaction, oxidation, reduction, fuel cells and rechargeable batteries properties of plastics — addition and condensation polymerisation including polythene and polyesters; representation of the structure of monomers and polymers, natural polymers fertilisers — the Haber process, commercial production of nitrate fertilisers, percentage mass compositions of fertilisers nuclear chemistry — radiation process, alpha, beta and gamma radiation; specific properties mass, charge and ability to penetrate different materials; nuclear equations; uses of radioactive isotopes; half-life; use of isotopes to date materials chemical analysis — techniques for monitoring the metals and alloys — reactivity series, reactions of metals, corrosion, physical and chemical protection of metals, electrochemical series and electrochemical cells, voltage and electroplating, extraction of metals displacement reactions, composition, uses and physical properties of alloys materials — polymers, monomers, name of polymers, thermosoftening and thermosetting plastics, properties, uses and combustion of plastics, biodegradable plastics; advantages and disadvantages of natural versus synthetic polymers, ceramic materials properties and uses; development of new materials unique properties; reuse and recycle materials fertilisers — plant nutrients and elements, natural and synthetic fertiliser nuclear chemistry — formation of elements and background radiation chemical analysis — qualitative analysis of the environment including pH, and flame testing Higher functional groups on solubility, boiling points and volatility. Aldehydes and ketones. Uses, carbonyl functional group, structural and molecular formulae. Oxidation. Effect of heat on proteins, denature of proteins. Oxidation of food, alcohols, hydrogen bonding. Diol, triols, primary, secondary and tertiary oxidation reactions. Carboxylic acids — reactions, including reduction and reactions with bases. Oxidation of edible oils. Antioxidants. Ion-electron equations for the oxidation. Soaps, detergents and emulsions. Hydrolysis of esters. Structure of soap ions including covalent tail (hydrophobic), and an ionic head (hydrophilic). Cleansing action of soaps. Production, action and use of detergents. Emulsion and emulsifiers and their formation and use in food. Fragrances — essential oils from plants: properties, uses and products. Terpenes — functional group, structure and use. Oxidation of terpenes within plants. Skin care — ultraviolet radiation (UV) in sunlight. Sunburn. Sun-block. Formation of free radicals in UV light. Structure, reactivity and reactions of free radicals. Free radical scavengers in cosmetic products, food products and plastics. Reaction of free radical scavengers with free radicals to prevent chain reactions. Chemistry in Society Getting the most from reactants — calculate quantities of reagents and products, and excess, % yield and atom economy, factors influencing the design of industrial process including cost availability of reactants and the environmental issues Equilibria — reversible reactions, dynamic equilibrium, altering equilibrium position, effect of catalyst on equilibrium and the most favourable reaction conditions Chemical energy — enthalpy, Hess’s law, and bond enthalpies Oxidising and reducing agents — elements, molecules and group ions as oxidising and reducing agents, electrochemical series as reduction reactions, ion electron redox equations, uses of strong oxidising agent Chemical analysis — chromatography and volumetric titrations National 3 In a hierarchy National 4 National 5 environment and methods for reducing pollution and titration with calculations In a hierarchy In a hierarchy Higher In a hierarchy Researching Chemistry Aim of this Unit is to develop skills relevant to undertaking research in Chemistry. No specified content in this Unit and the topic chosen by the learner will determine the key area to be developed. The Unit has 3 Outcomes as follows: 1) Apply skills of scientific inquiry and draw on knowledge and understanding to research the underlying chemistry 2) Apply skills of scientific inquiry to investigate, through experimentation, the underlying chemistry 3) Draw on knowledge, understanding and skills to prepare a scientific communication for the practical investigation SKILLS, KNOWLEDGE AND UNDERSTANDING using, with guidance, chemistry knowledge and understanding solving simple problems and making decisions planning and safely carrying out experiments/practical investigations using, with guidance, information handling skills, including collecting, presenting and processing information making basic generalisations from evidence/information drawing valid conclusions from evidence/information communicating findings/information demonstrating knowledge and understanding by making statements, describing information, providing explanations applying knowledge of chemistry to familiar situations, interpreting information and solving problems planning experiments to illustrate a particular effect, applying safety measures carrying out straightforward experimental procedures, safely, recording general observations and collecting data applying information handling skills including selecting, presenting and processing information making generalisations based on evidence/information drawing valid conclusions and giving explanations supported by evidence suggesting improvements to experiments/ investigations communicating findings/information demonstrating knowledge and understanding of chemistry by making statements, describing information, providing explanations and integrating knowledge applying knowledge of chemistry to new situations, interpreting information and solving problems planning and designing experiments/investigations to test given hypotheses or to illustrate particular effects carrying out experimental procedures safely, recording observations and collecting data selecting and presenting information appropriately in a variety of forms processing information (using calculations and units, where appropriate) making predictions and generalisations based on evidence/information drawing valid conclusions and giving explanations supported by evidence/justification identifying a source of error and suggesting improvements to experiments/ investigations communicating findings/information demonstrating knowledge and understanding of chemistry by making statements, describing information, providing explanations and integrating knowledge applying knowledge of chemistry to new situations, interpreting information and solving problems planning or designing experiments safely carrying out experiments, recording detailed observations and collecting data selecting and presenting information appropriately in a variety of forms processing information (using calculations, significant figures and units, where appropriate) making predictions and generalisations from evidence/information drawing valid conclusions and giving explanations supported by evidence/justification evaluating experimental procedures by identifying sources of error and suggesting improvements communicating findings/information