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Importance of Materials Processing All electronic devices & systems are made of materials in various combinations Raw materials are far from the final electronic products Semiconductor materials (e.g., Si, Ge, GaAs, GaN...) used for devices must be of extremely high purity and crystalline order Real Materials and their Processing Particles, lines and rigid bodies vs. real materials Material-specific properties determine the function and processing details of a material Comprehensive knowledge of materials processing requires ~ 5-10 years of learning and practice Advantage and role of physics students Different Types of Electronic Devices Discrete devices: diodes, transistors, rectifiers, sensors, … Integrated circuits (IC): CPU, DRAM, ASIC, … Opto-electronics: LED, semiconductor laser (in CD/VCD players, optical communication), display, lighting, … Solar cells: on satellites, calculators, large-scale power generation Data storage: DRAM, hard disk, ZIP, flush memory, CD-ROM, ... Electro-mechanic devices: electro-magnetic, piezo-electric, ... Different Electronic Materials Semiconductors: Elemental (Si, Ge) & Compound (GaAs, GaN, ZnS, CdS, …) Insulators: SiO2, Al2O3, Si3N4, SiOxNy, ... Conductors: Al, Au, Cu, W, silicides (metal-Si compounds), ... Organic and polymer: liquid crystal, insulator, semiconductor, conductor Composite materials: multi-layer structures, nano-materials, photonic crystals, ... More: magnetic, superconductor, bio-material, … Cubic Lattices and Main Crystal Faces Z Y X Lattice Structures of Semiconductors Si Ga Si Si Si Ga Si Si Si Ga As As Si Ga Si Ga Si Ga Ga Si Si As Si Si Si Silicon, a = 5.43 Å (diamond structure) As Ga Si Si Ga Ga Si Ga Ga Ga GaAs, a = 5.65 Å (zincblende structure) Ga Point Defects impurities 1D & 2D Defects Edge Dislocation Real Device Structures in IC metal contacts n+ p n Diode Bipolar transistor MOSFET N-channel MOSFET (Metal-oxide-semiconductor FET) Primary flat edge along [110] Schematic vs. Real Secondary flat Si(001) wafer Fabrication of a Diode wafer cut diffusion oxidation lithography diffusion (f) metallization Processes involved in Semiconductor device and IC manufacture Crystal growth and wafer preparation Epitaxy Diffusion Ion implantation Oxidation Lithography Diffusion Etching Deposition Connection Testing Packaging