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thermodynamics
thermodynamics

... surroundings, with fixed values of pressure, volume, temperature, mass and composition that do not change with time, is in a state of thermodynamic equilibrium. In general, whether or not a system is in a state of equilibrium depends on the surroundings and the nature of the wall that separates the ...
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... •� Work and heat are not state functions; they are path dependent- what does this mean? In most physical situations, we are concerned with a quantity of heat or work transferred into or out of a material, which causes a change from one state of the material to another. Path dependence implies that t ...
No Slide Title - McMaster Chemistry
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PREPARATORY PROBLEMS
PREPARATORY PROBLEMS

... applied to macrosystems. To illustrate this idea, E. Schrödinger proposed the following mental experiment. Consider the Geiger counter which detects the entering electrons. The counter is connected to a device which breaks the glass with the poison when the particle enters the counter. Near the glas ...
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PREPARATORY PROBLEMS (Theoretical)

... applied to macrosystems. To illustrate this idea, E. Schrödinger proposed the following mental experiment. Consider the Geiger counter which detects the entering electrons. The counter is connected to a device which breaks the glass with the poison when the particle enters the counter. Near the glas ...
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General Chemistry Questions
General Chemistry Questions

... 6. Two solutions (the system), each of 25.0 mL volume and at 25.0 °C, are mixed in a beaker. A reaction occurs between them, causing the temperature to drop to 20.0 °C. After the products have equilibrated with the surroundings, the temperature is again 25.0 °C and the total volume is 50.0 mL. No ga ...
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Chemical thermodynamics



Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes.The structure of chemical thermodynamics is based on the first two laws of thermodynamics. Starting from the first and second laws of thermodynamics, four equations called the ""fundamental equations of Gibbs"" can be derived. From these four, a multitude of equations, relating the thermodynamic properties of the thermodynamic system can be derived using relatively simple mathematics. This outlines the mathematical framework of chemical thermodynamics.
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