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determining oxidation numbers
determining oxidation numbers

... 1. The oxidation number (ON) for any element is zero. 2. For monatomic ions, the ON is equal to the charge on the ion. 3. Fluorine always has an ON = -1 in compounds. 4. The ON for oxygen is -2 in compounds, except in peroxides, when it is 1, or bound to fluoride, when it is +2. 5. Other halogens ha ...
Stability of complexes of metal ions in aqueous solution.
Stability of complexes of metal ions in aqueous solution.

... The inner and outer sphere of waters around metal ions in solution: In the solid state, the H-atoms of the coordinated waters are almost always H-bonded to other waters, or anions such as nitrate or perchlorate. In aqueous solution, this H-bonding structures the water molecules around the aqua ion ...
xes, except for the mono-complex which was regu
xes, except for the mono-complex which was regu

... xes, except for the mono-complex which was regular octahedral, had shorter Ni-O bonds than Ni-N bonds, and the differences between the Ni-O and Ni-N distances were more enhanced in the tris-complex than in the bis-complex. Stepwise formation constants of the glycinato complexes decreased with the nu ...
Chapter 1 Structure and Bonding
Chapter 1 Structure and Bonding

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1.4 Desirable Features of Inorganic Sensor Materials
1.4 Desirable Features of Inorganic Sensor Materials

Syntheses and X-ray crystallographic studies of {[Ni(en)2(pot)2]0.5
Syntheses and X-ray crystallographic studies of {[Ni(en)2(pot)2]0.5

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Synthesis and Spectroscopy Study of the New Amide Complexes of

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1- - International Journal of ChemTech Research
1- - International Journal of ChemTech Research

... functions. It has been shown that this approach is well suited for the study of this kind of systems, yielding binding energies in good agreement with experimental values. The corresponding Ni2+ binding energies, D0, were evaluated by subtracting from the energy of the complex the energy of the neut ...
Cr2(SO4)3∙n H2O
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... dot. The name includes waters of hydration at the end showing its numerical prefix as in 4 above followed by hydrate (ex. hexahydrate for ∙6H2O). Note that often some or all of these waters of hydration are coordinated to the metal ion. Sometimes “anhydrous” is put before the name to emphasize that ...
Mixed ligand transition metal(II) complexes of Knoevenagel
Mixed ligand transition metal(II) complexes of Knoevenagel

... The coo rdinati on co mpl exes of 2,4-pentanedi one and its deri vat ive Iigands have aroused co nsiderab le interest ove r (ew decades ' ·'. It is we ll kn ow n th at the enoli c proton of th e predomin ant ly ex istin g enol fo rm of 2,4- pentan ed ione undergoes di ssociat ion to form a number of ...
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... 14.The Hall process for the production of aluminum involves the reaction of aluminum oxide with elemental carbon to give aluminum metal and carbon monoxide. If the yield of this reaction is 75%, what mass of aluminum metal can be produced from the reaction of 1.65  106 g of aluminum oxide with 1.50 ...
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IR & UV-vis Spectroscopy
IR & UV-vis Spectroscopy

... NOTE: it is important to distinguish between the words “clear” and “colorless.” Neither AP, nor IB, will give credit for use of the word clear (which means translucent) when colorless should have been used. Think about it, something can be pink and clear… colorless means something else. ...
Transition metal complexes_bonding
Transition metal complexes_bonding

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F. ELECTRONIC SPECTRA OF COORDINATION COMPOUNDS

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Aquatic Geochemistry

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EXAM REVIEW !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! The examination is scheduled
EXAM REVIEW !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!! The examination is scheduled

... you will again be provided with a sheet of equations that you may need to solve a particular problem but you may be asked to derive an eqn. in one or more instance. There will be more eqns. than you need. You will be expected to know basic equations like the ideal gas law. Remember if you set up the ...
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Transition-Metal Complexes with the Novel Scorpionate Ligand

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Stability constants of complexes

A stability constant (formation constant, binding constant) is an equilibrium constant for the formation of a complex in solution. It is a measure of the strength of the interaction between the reagents that come together to form the complex. There are two main kinds of complex: compounds formed by the interaction of a metal ion with a ligand and supramolecular complexes, such as host-guest complexes and complexes of anions. The stability constant(s) provide the information required to calculate the concentration(s) of the complex(es) in solution. There are many areas of application in chemistry, biology and medicine.
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