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112 Ex IV LEC OUTLINE F04
112 Ex IV LEC OUTLINE F04

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ChE 215, Physical Chemistry

... The objective of this course is to introduce the basic topics in Kinetics, Thermodynamics and Statistical Mechanics. In fact this course present collection of distinct topics particularly useful to chemical engineering students. The basic principles in the course are demonstrated by six experiments ...
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... The Chemical elements and its compounds : (a) (i) Group trends and periodic trends of effective nuclear charge, atomic and ionic radii, ionisation energies, electron affinity and electronegativity with respect to s-, p-, d- block elements. (ii) General trends of variation of electronic structures, e ...
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Reaction progress kinetic analysis

In chemistry, reaction progress kinetic analysis (RPKA) is a subset of a broad range of kinetic techniques utilized to determine the rate laws of chemical reactions and to aid in elucidation of reaction mechanisms. While the concepts guiding reaction progress kinetic analysis are not new, the process was formalized by Professor Donna Blackmond (currently at Scripps Research Institute) in the late 1990s and has since seen increasingly widespread use. Unlike more common pseudo-first-order analysis, in which an overwhelming excess of one or more reagents is used relative to a species of interest, RPKA probes reactions at synthetically relevant conditions (i.e. with concentrations and reagent ratios resembling those used in the reaction when not exploring the rate law.) Generally, this analysis involves a system in which the concentrations of multiple reactants are changing measurably over the course of the reaction. As the mechanism can vary depending on the relative and absolute concentrations of the species involved, this approach obtains results that are much more representative of reaction behavior under commonly utilized conditions than do traditional tactics. Furthermore, information obtained by observation of the reaction over time may provide insight regarding unexpected behavior such as induction periods, catalyst deactivation, or changes in mechanism.
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