• Study Resource
  • Explore Categories
    • Arts & Humanities
    • Business
    • Engineering & Technology
    • Foreign Language
    • History
    • Math
    • Science
    • Social Science

    Top subcategories

    • Advanced Math
    • Algebra
    • Basic Math
    • Calculus
    • Geometry
    • Linear Algebra
    • Pre-Algebra
    • Pre-Calculus
    • Statistics And Probability
    • Trigonometry
    • other →

    Top subcategories

    • Astronomy
    • Astrophysics
    • Biology
    • Chemistry
    • Earth Science
    • Environmental Science
    • Health Science
    • Physics
    • other →

    Top subcategories

    • Anthropology
    • Law
    • Political Science
    • Psychology
    • Sociology
    • other →

    Top subcategories

    • Accounting
    • Economics
    • Finance
    • Management
    • other →

    Top subcategories

    • Aerospace Engineering
    • Bioengineering
    • Chemical Engineering
    • Civil Engineering
    • Computer Science
    • Electrical Engineering
    • Industrial Engineering
    • Mechanical Engineering
    • Web Design
    • other →

    Top subcategories

    • Architecture
    • Communications
    • English
    • Gender Studies
    • Music
    • Performing Arts
    • Philosophy
    • Religious Studies
    • Writing
    • other →

    Top subcategories

    • Ancient History
    • European History
    • US History
    • World History
    • other →

    Top subcategories

    • Croatian
    • Czech
    • Finnish
    • Greek
    • Hindi
    • Japanese
    • Korean
    • Persian
    • Swedish
    • Turkish
    • other →
 
Profile Documents Logout
Upload
Optional Molecular Shapes Project – Due Monday 5/14/12 You will
Optional Molecular Shapes Project – Due Monday 5/14/12 You will

... Optional Molecular Shapes Project – Due Monday 5/14/12 You will create a presentation using the application of your choice (Animoto, Glogster, PhotoPeach, VoiceThread, WIX, Prezi). You will include the information presented below in your presentation. Finally, you will submit the link to your publis ...
Equilibrium
Equilibrium

... ● Electronegativity: ability of an atom in a molecule to attract shared electrons to itself; increases across a period and decreases down a family ● Ionization Energy: energy required to remove the valence electron from an atom; increases across a period and increases up a family ● Atomic Radius: ra ...
Carbene Singlets, Triplets, and the Physics that
Carbene Singlets, Triplets, and the Physics that

... When this linear combination model is used, one talks of the change in energy experienced by the electrons in terms of constructive or destructive interference of their atomic (molecular, in the likely event of two molecules interacting) orbitals, resulting in a mixing of pure orbitals. This mixing ...
Ch. 3
Ch. 3

... The oxidations number indicates if an atom is going to give up electrons or take in electrons in order to become stable. Positive oxidation numbers mean the atom is going to give up electrons. ...
sample - Bright Red Publishing
sample - Bright Red Publishing

... Each line in an emission spectrum is due to a transition between definite energy levels. Using the frequency or wavelength of each line, it is possible to calculate the energy difference between energy levels. The structure of the atom as drawn above with electrons orbiting a central positive nucleu ...
Molecular geometry
Molecular geometry

...  Valence bond theory (VB): An advanced model of chemical bonding in which electrons reside in quantum-mechanical orbitals localized on individual atoms that are a hybridized blend of standard atomic orbitals; chemical bonds result from an overlap of these orbitals.  Molecular orbital theory (MO): ...
Chapter 4 Review, pages 262–267
Chapter 4 Review, pages 262–267

... Carbon also forms a covalent bond. It will share its 4 valence electrons with electrons from other atoms it bonds with. If carbon were to gain 4 electrons, it would be very difficult for carbon’s 6 protons to hold onto 10 electrons. For carbon to lose 4 electrons would require a large quantity of en ...
CHEM 1411 NAME: PRACTICE EXAM #3 (Chapters 6
CHEM 1411 NAME: PRACTICE EXAM #3 (Chapters 6

Hydrogen Bonding
Hydrogen Bonding

... outermost orbital to undergo chemical changes It is the cardinal rule of bonding. It is the gain in stability when atoms have a full complement of eight electrons in their valence shells. The bonding in carbon dioxide (CO2): all atoms are surrounded by 8 electrons, fulfilling the octet rule ...
Covalent Bonding and Molecular Structures
Covalent Bonding and Molecular Structures

1Molecule Shapes
1Molecule Shapes

... molecules, and (3) an expanded octet. Incomplete Octet: In some compounds, the number of electrons surrounding the central atom in a stable molecule is fewer than eight. Beryllium is an alkaline earth metal and so may be expected to form ionic bonds. However, its very small size and somewhat higher ...
Science Olympiad
Science Olympiad

... (B) atomic radius decreases due to an increase in effective nuclear charge. (C) electronegativity decreases due to an increase in atomic radius. (D) electron affinity decreases due to an increase in effective nuclear charge. (E) ionization energy increases due to an increase in atomic radius. ______ ...
How to Determine the Molecular Geometry for a Compound
How to Determine the Molecular Geometry for a Compound

... DO NOT count Lone Pair electrons on the atoms which are connected to the central atom. ONLY the lone pairs of electrons on the central atom count as E’s. 3. The total number of X’s and E’s determine the ELECTRON PAIR geometry. (There are only 5 basic electron pair geometries) ...
The Periodic table
The Periodic table

...  A region of space within an electron subshell where an electron with a specific energy is most likely to be found.  S subshell=1 orbital, p subshell=3 orbitals, d subshell=5 orbitals, f subshell=7 orbitals.  Maximum number of electrons in a subshell is always 2.  S orbital=spherical, p orbital ...
The Chemical Context of Life
The Chemical Context of Life

Chemistry 101 11-MOLECULAR GEOMETRY In this experiment
Chemistry 101 11-MOLECULAR GEOMETRY In this experiment

Campbell Biology, 10e (Reece) Chapter 2 The Chemical Context of
Campbell Biology, 10e (Reece) Chapter 2 The Chemical Context of

... become oppositely charged B) protons and neutrons are shared by two atoms so as to satisfy the requirements of both atoms C) outer-shell electrons of two atoms are shared so as to satisfactorily fill their respective orbitals D) outer-shell electrons of one atom are transferred to fill the inner ele ...
pblock - Chemistry Courses
pblock - Chemistry Courses

... 2nd period: Only s and p orbitals are possible with n = 2 Therefore, the maximum number of bonds is 4 (single and/or double bonds) Examples: CH4, NF4+, BH43rd (and higher periods): can use d-orbitals to make bonds E.g. ...
Bonding Nomenclature Notes
Bonding Nomenclature Notes

... ending second. 3) Add prefixes to both indicating the number of atoms of each element ...
Section 3.6
Section 3.6

... quantum number might be n = 2, l = 1, ml = –1, and ms = +1/2 . This might describe an electron in a hydrogen atom in an “excited” state. 7. For each principal quantum number from n = 1 to n = 3 (see Table 4), there can be 2, 8, and 18 different electron descriptions. 8. In the development of scienti ...
Molecular Geometry VSEPR Theory
Molecular Geometry VSEPR Theory

... Ex: CH4 has 4 “things” so its tetrahedral ...
Molecular Shapes Project Due April 21, 2011 at Midnight You will
Molecular Shapes Project Due April 21, 2011 at Midnight You will

Bio_130_files/Chemistry Review
Bio_130_files/Chemistry Review

Bio_130_files/Chemistry Review
Bio_130_files/Chemistry Review

... properties. They are charted on the periodic table based on some of their chemical characteristics. • There are 24 major elements that have various roles in the body. – These include structural, enzymatic, and homeostatic balance. • Compounds, like water, are formed by combining the atoms of differe ...
1) - Kurt Niedenzu
1) - Kurt Niedenzu

< 1 ... 24 25 26 27 28 29 30 31 32 ... 53 >

Bent's rule



Bent's rule describes and explains the relationship between the isovalent hybridization of central atoms in molecules and the electronegativities of substituents. The rule was stated by Henry Bent as follows: ""Atomic s character concentrates in orbitals directed toward electropositive substituents"".The chemical structure of a molecule is intimately related to its properties and reactivity. Valence bond theory proposes that molecular structures are due to covalent bonds between the atoms and that each bond consists of two overlapping and typically hybridised atomic orbitals. Traditionally, p-block elements in molecules are assumed to hybridise strictly as spn, where n is either 1, 2, or 3. In addition, the hybrid orbitals are all assumed to be equivalent (i.e. the n+1 spn orbitals have the same p character). Results from this approach are usually good, but they can be improved upon by allowing hybridised orbitals with noninteger and unequal p character. Bent's rule provides a qualitative estimate as to how these hybridised orbitals should be constructed. Bent's rule is that in a molecule, a central atom bonded to multiple groups will hybridise so that orbitals with more s character are directed towards electropositive groups, while orbitals with more p character will be directed towards groups that are more electronegative. By removing the assumption that all hybrid orbitals are equivalent spn orbitals, better predictions and explanations of properties such as molecular geometry and bond strength can be obtained.Bent's rule can be generalized to d-block elements as well. The hybridisation of a metal center is arranged so that orbitals with more s character are directed towards ligands that form bonds with more covalent character. Equivalently, orbitals with more d character are directed towards groups that form bonds of greater ionic character.
  • studyres.com © 2025
  • DMCA
  • Privacy
  • Terms
  • Report